Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Section 1 of 16 · Rapid response

SDS Section 1: Identification

Section 1 is what ties a document to a container. It carries no hazard data at all — only the identifier that must match the label, what the product may and may not be used for, and the telephone number that has to answer.

Mandatory in the EU Mandatory under OSHA HCS 18 required items (EU)
What this section must contain →

01 · At a glance

What section 1 of an SDS contains

Who made the product, what it is called, what it may and may not be used for, and the emergency telephone number.

Legal text Heading as printed Status
EU SECTION 1: Identification of the substance/mixture and of the company/undertaking REACH Annex II, as amended by Regulation (EU) 2020/878 Mandatory
US 1. Identification OSHA HCS, 29 CFR 1910.1200 Appendix D Mandatory
UN 1. Identification GHS Rev. 11, Annex 4 (A4.2.3.1) Recommended

The numbering is harmonised worldwide; the wording is not. The UN GHS is a model text with no legal force of its own — it becomes binding only where a country adopts it, which is why the EU and US columns are the ones an inspector reads from.

02 · Required content

Section 1 checklist

Every item the regulation requires under this heading. Switch jurisdiction to see how the requirement actually changes — this is not the same list with different labels.

Jurisdiction
0 / 0 items ticked

Reference aid, not a legal audit. The checklist reproduces the structure the regulation requires; whether the content under each heading is adequate for your product is a judgment only the person who classified it can make.

03 · Guidance

The section that ties a document to a container

A safety data sheet is only worth reading if you can show it belongs to the thing in front of you. That proof is section 1 — which is why identification comes before classification. Someone has to establish that this sheet describes this drum before anyone acts on the statement that the contents are corrosive.

All three texts build the section from the same five parts: an identifier that matches the label, the other names the product goes by, what it is and is not for, who supplies it, and a number that answers in an emergency. They part company on how much is prescribed. OSHA’s Appendix D prints five lettered items and stops; REACH Annex II runs to four subsections with a dozen obligations packed inside the first one, several introduced by Regulation (EU) 2020/878 and still absent from sheets not revised since.

1.1 — the identifier, and everything the EU bolted onto it

The name is not the sheet’s to choose

Annex II does not define the product identifier. It routes it: to Article 18(2) of the CLP Regulation for a substance, to Article 18(3)(a) for a mixture. Then it adds the test that matters operationally — the identifier must be as provided on the label, in the official language(s) of the Member State where the product is placed on the market, unless that Member State provides otherwise. The UN text is blunter still: GHS Annex 4 A4.3.1.1 says the identity should be exactly as found on the label, and OSHA’s item (a) says the same in three words — “Product identifier used on the label.”

So the first line of section 1 is a copy, not a marketing name. Where a commercial name has drifted from the label — a rebrand, a regional variant, a reformulation that kept the old code — the sheet has quietly stopped being the sheet for that container.

Registration numbers, and a derogation with a clock attached

For substances subject to registration, subsection 1.1 requires the identifier to be consistent with the registration and the registration number under Article 20(3) of REACH to be indicated as well.

Then comes a provision most readers skim as an exemption. A distributor or downstream user may omit the part of that number identifying the individual registrant of a joint submission — but only against the two conditions printed as (a) and (b), the sharper of which is a seven-day deadline for putting the full number in front of the enforcement authority. A supplier who cannot meet that clock was never inside the derogation, and the shortened number on his sheet is not an abbreviation but an incomplete registration number.

Forms, nanoforms, and one sheet covering several products

Two further allowances in 1.1 are read as conveniences and are in fact conditions. One sheet may cover several substances or mixtures — only where it fulfils the Annex for each of them, the UN text adding that all names and variants be listed or the range clearly delineated. One sheet may cover different forms of a substance — only where it makes clear which information belongs to which form.

And then the sentence a great many sheets still do not carry: if the safety data sheet pertains to one or more nanoforms, or to substances that include nanoforms, this shall be indicated by using the word “nanoform”. The obligation is unusually literal — particle size data in section 9 does not discharge it. The word itself has to be in this subsection.

The UFI, and why it belongs here rather than anywhere else

The unique formula identifier is created under section 5 of Part A of Annex VIII to CLP: a unique alphanumeric code that unambiguously links a mixture to the composition information its supplier submitted for emergency health response. Annex VIII normally requires it on the label, preceded by the acronym “UFI” in capital letters, clearly visible, legible and indelibly marked.

By derogation, for hazardous mixtures for industrial use and for mixtures which are not packaged, it may instead be indicated in the safety data sheet — and Annex II then requires it in subsection 1.1, not in section 15, not in section 16, not in a footer. For an industrial-use mixture, section 1 may be the only place the UFI exists at all, so putting it elsewhere does not misfile it, it hides it.

1.2 — what it is for, and what it is not for

Subsection 1.2 asks two things, and most sheets answer only the first.

The first is at least a brief description of the identified uses relevant to the recipient. Annex II’s own examples set the register expected — floor cleaning, industrial use in polymer production, professional use in cleaning agents. “Industrial use” on its own is not a description of a use; it is a market segment. The UN text goes further still and asks what the product actually does, its examples being flame retardant and anti-oxidant.

The second is the uses the supplier advises against, and the reasons why. The list need not be exhaustive, but where it applies the reason is part of the obligation, not a courtesy: a bare prohibition tells a downstream user nothing about whether their own application falls inside it.

Where a chemical safety report is required, 1.2 becomes a consistency test — it must agree with the identified uses in that report and with the exposure scenarios annexed to the sheet. That is the hinge between section 1 and the technical half of the document.

1.3 and 1.4 — who answers, and on which telephone

The supplier is a role, not a company type

Annex II names five possibilities — manufacturer, importer, only representative, downstream user or distributor — and requires whichever one supplies the sheet to be identified, with a full address and telephone number, as well as an e-mail address for a competent person responsible for the safety data sheet. That last requirement has no US and no UN counterpart, and it is what makes an EU sheet auditable: a named function is accountable for the contents.

One more provision under 1.3 is worth noticing for what it does not require: where an only representative has been appointed, details of the non-Union manufacturer or formulator may be provided. Permitted, not required — which is why the actual maker of an imported substance is so often invisible on an EU sheet.

The US text is narrower. Appendix D item (d) asks for the name, U.S. address and U.S. telephone number of the chemical manufacturer, importer or other responsible party. A sheet arriving in a US workplace carrying only a European head office does not satisfy it, however complete that address is.

The emergency number

Both texts require references to emergency information services. The EU adds a default the US does not have: where an official advisory body exists in the Member State where the product is placed on the market — this may be the body responsible for receiving health-related information under Article 45 of CLP — its number shall be given, and can suffice.

Both then attach the same honesty condition, and it is the one most routinely broken: if availability is limited for any reason, such as hours of operation, or if there are limits on the types of information provided, that must be clearly stated. An unqualified switchboard number implies cover the supplier may not actually provide, at the one moment the reader has no way to check.

How section 1 connects to the rest of the sheet

  • Section 1 carries no hazard information whatsoever. Everything about danger is in section 2; a reader who stops at section 1 has read the cover, not the sheet.
  • Section 1 names the product, section 3 names what is inside it. On a single-substance sheet the two converge, and a disagreement between them is the fastest way to spot a document assembled from two sources.
  • The identified uses in 1.2 are what the engineering controls in section 8 must be adequate for — Annex II ties subsection 8.2.1 back to 1.2 by name.
  • The emergency number in 1.4 supplements, and does not replace, section 4. Where the first-aid measures are thin, that number is doing work it was never meant to do alone.
  • Whether a chemical safety assessment was carried out is recorded in section 15 — and if one was, 1.2 has to match it.
  • The revision date in section 16 tells you whether the section 1 you are reading is current. An emergency number three revisions out of date is worse than none, because it will be dialled.

What a good section 1 looks like

Three tests, all answerable by reading:

  1. Can you match it to the container without judgment? The identifier on the page is the identifier on the label, in the language of the market it was sold into. If you have to reason about whether these are the same product, they are not demonstrably the same product.
  2. Does it say what the product is for, in words the recipient recognises? “Floor cleaning” is a use. “Industrial” is a segment. And where the supplier advises against a use, the reason is printed alongside.
  3. Would the number in 1.4 answer, right now? A named service, with its hours and scope stated — and in the EU, the official advisory body of the Member State the product was placed on the market in, where one exists.

Where the EU and the US disagree in section 1

A sheet written to satisfy one of these can fail the other. These are the points where the two texts genuinely require different things.

Point EU — REACH Annex II US — OSHA App. D
Where the supplier must be reachable Full address and telephone number of the supplier, plus a full address and telephone number for a responsible person nominated in the Member State of placing on the market, where the supplier is not located there. “Name, U.S. address, and U.S. telephone number of the chemical manufacturer, importer, or other responsible party.” The address itself has to be a US one.
A named person accountable for the sheet 1.3 requires an e-mail address for a competent person responsible for the safety data sheet. Not required. Appendix D asks for a company name, address and telephone number, and stops there.
Registration number For substances subject to registration, the number assigned under Article 20(3) of REACH must be indicated in 1.1, with a conditional derogation for distributors and downstream users carrying a 7-day enforcement deadline. No registration regime and no equivalent identifier.
Unique formula identifier Where a mixture has a UFI under Annex VIII to CLP and that UFI is indicated in the sheet, it must be given in subsection 1.1. No UFI. Poison-centre notification is not part of the Hazard Communication Standard.
Nanoforms A sheet pertaining to one or more nanoforms, or to substances that include nanoforms, must say so using the word “nanoform”. The five lettered items under section 1 of Appendix D say nothing about nanoforms.
Uses advised against 1.2 requires the uses the supplier advises against and the reasons why, where applicable. (c) asks for “restrictions on use”. The reasons are not part of the requirement.
Which emergency number Where an official advisory body exists in the Member State of placing on the market — such as the Article 45 body under CLP — its number shall be given and can suffice. “Emergency phone number”, with no designated body and no default.
Consistency with a chemical safety report Where a CSR is required, 1.2 must match its identified uses and the exposure scenarios annexed to the sheet; 1.3 must match the identity given in the registration. No chemical safety report, so no consistency test on section 1 at all.

05 · Failure modes

What gets section 1 rejected

Common error

The name on the sheet is not the name on the drum

All three texts fix the identifier to the label: Annex II requires it as provided on the label, GHS Annex 4 says exactly as found on the label, and Appendix D item (a) says “product identifier used on the label”. A rebrand, a regional variant or a reissued product code that reaches the label but not the sheet breaks the only link between the document and the container.

Common error

A 24-hour number that is not 24 hours

Annex II 1.4 and GHS A4.3.1.5 both require limits on the service to be clearly stated — hours of operation, or limits on the types of information provided. An office switchboard printed as an emergency number, with no qualification, implies cover the supplier does not provide.

Common error

One sheet for a family, with the family never named

Annex II allows one sheet to cover more than one substance or mixture only where it fulfils the Annex for each of them, and GHS A4.3.1.1 requires all names and variants to be listed or the range to be clearly delineated. A generic sheet headed with one trade name and silently used for six grades satisfies neither.

Common error

The registrant part dropped without the conditions being met

The derogation in 1.1 is not an exemption — it is conditional on points (a) and (b). A distributor who cannot produce the full registration number, or forward the request, within 7 days of an enforcement request was never inside it, and the truncated number on his sheet is simply incomplete.

Common error

The UFI parked in section 15 or 16

Where a mixture has a UFI and it is indicated in the safety data sheet, Annex II requires it in subsection 1.1. For hazardous mixtures for industrial use and for mixtures that are not packaged, Annex VIII to CLP allows the sheet to be the only place the UFI appears at all — so a reader who cannot find it in section 1 will reasonably conclude there is none.

Common error

“Industrial use” given as the identified use

Subsection 1.2 asks for at least a brief description of the identified uses relevant to the recipient, and the Annex's own examples — floor cleaning, industrial use in polymer production, professional use in cleaning agents — show the level intended. A market segment is not a description of a use, and where a chemical safety report exists it will not match the uses assessed in it.

06 · On a real substance

See section 1 filled in

Pick a substance and go straight to its section 1. These are our own reference pages — harmonised classification from CLP Annex VI, a computed storage verdict and sourced response data — not supplier PDFs.

Substance 109 of 109

The substance pages do not carry a separate section 1 block yet, so these links open the page itself.

08 · FAQ

Frequently asked questions

What does section 1 of the SDS contain?

Five things, in all three legal texts. The product identifier — the name printed on the label, so the sheet can be matched to the container. Other means of identification: synonyms, company product codes, and in the EU the unique formula identifier of a mixture. The relevant identified uses, and the uses the supplier advises against. The details of the supplier — name, full address, telephone number, and in the EU an e-mail address for a competent person responsible for the sheet. And an emergency telephone number, with any limit on its hours or its scope clearly stated. Section 1 contains no hazard information at all.

What does section 1 of an SDS indicate?

It indicates identity and accountability, not danger. Nothing in section 1 tells you whether a product is hazardous — that is section 2. What it does tell you is whether the sheet in your hand describes the container in front of you, which company must answer for the document's contents and at which address, whether the use you have in mind is one the supplier identified or one it explicitly advises against, and which telephone number to call when something goes wrong. In the EU it also indicates whether the substance is supplied as a nanoform, and carries the UFI for a mixture.

What is the UFI in section 1 of an SDS?

The unique formula identifier is created under section 5 of Part A of Annex VIII to the CLP Regulation. It is a unique alphanumeric code that unambiguously links the mixture to the composition information its supplier submitted for emergency health response, so the formulation can be retrieved without the supplier being reachable. Annex VIII normally requires it on the label, preceded by the acronym “UFI” in capital letters. By derogation, for hazardous mixtures for industrial use and for mixtures that are not packaged, it may instead be indicated in the safety data sheet — and REACH Annex II then requires it to appear in subsection 1.1.

Does section 1 have to say “nanoform”?

Yes, where it applies. REACH Annex II, subsection 1.1, as amended by Regulation (EU) 2020/878, states that if the safety data sheet pertains to one or more nanoforms, or to substances that include nanoforms, this shall be indicated by using the word “nanoform”. The requirement is unusually literal: the word itself has to appear, not merely the particle data further down the sheet. The same subsection also allows one sheet to cover different forms of a substance, provided it makes clear which information relates to which form — otherwise a separate sheet is prepared per form or group of forms. OSHA's Appendix D has no equivalent.

Does the emergency number in section 1 have to answer 24 hours a day?

No. Neither REACH Annex II nor the UN GHS text requires round-the-clock cover. Both require honesty about the cover that exists: Annex II 1.4 says that if availability is limited for any reason, such as hours of operation, or if there are limits on the specific types of information provided, this shall be clearly stated. GHS Annex 4 gives the shape of that disclosure — hours such as Monday to Friday, 8:00 a.m. to 6:00 p.m., or 24 hours, and scope such as medical or transport emergencies. In the EU, where an official advisory body exists in the Member State of supply, its number shall be given and can suffice.

What is the difference between sections 1 and 8 of an SDS?

They answer different questions and are read at different moments. Section 1 identifies the product and the company behind it: product identifier, identified uses and uses advised against, supplier address, emergency telephone number. Section 8 sets out exposure controls and personal protection — the occupational exposure limits that apply, the engineering controls, and the protective equipment. Section 1 is what you read to confirm the sheet belongs to the drum in front of you; section 8 is what you read before you open it. The two are linked: REACH Annex II ties the engineering controls in 8.2.1 back to the identified uses named in subsection 1.2.

Last reviewed 2026-08-03. This page describes what the regulations require under section 1; it is not a substitute for the safety data sheet of the product you actually hold, or for professional advice on classifying it.

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