Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.
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Safety data sheet reference · CAS 74-98-6

Propane SDS

also: propane MSDS · safety data sheet · C3H8 · CAS 74-98-6 · EC 200-827-9 · LPG

Danger · Flam. Gas 1 UN 1978 · ADR 2
Flame GHS02 Gas Cylinder GHS04

Official PDF from supplier

This page is a reference, not the legal document.

CAS number

74-98-6

EC number

200-827-9

CLP Annex VI index

601-003-00-5

§ 02 · Hazards identification

Harmonised EU classification

CLP Annex VI · Index 601-003-00-5. A supplier SDS may add self-classified hazards — this is the legal minimum.

H220 Extremely flammable gas. Flammable gas — Category 1 (Flam. Gas 1)

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P403 Store in a well-ventilated place.

§ 07 · Handling and storage

Computed storage verdict

§ 09 · Physical and chemical properties

Measured properties

The full physical-property table (melting/boiling point, flash point, explosion limits, vapour pressure, density) is being populated for this substance from ECHA registration data and will appear here as it lands.

§ 10 · Stability and reactivity

Reactive group (CAMEO/NOAA): Hydrocarbons, Aliphatic Saturated. Our database documents 3 incompatible and 6 caution reaction-partner groups for propane — including which combinations release gas on contact. See the per-partner breakdown with gas release →

3

Incompatible

6

Caution

§ 13 · Disposal considerations

Dispose of waste and residues in accordance with local and national regulations — in the EU under the Waste Framework Directive 2008/98/EC. Never discharge to drains or municipal waste; hand contaminated packaging and unused product to an authorised waste-disposal company. The supplier's SDS section 13 lists the applicable waste codes for the specific product.

§ 14 · Transport information

Road transport — ADR 2025

UN number

UN 1978

Proper shipping name

PROPANE

Class · PG

2

Classification code

2F

Transport category

2

ADR labels

2.1

Hazard ID (Kemler) / UN plate

23
1978

Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.

Source: UN ADR 2025 (ECE/TRANS/352), Table A. Road (ADR) only — for sea (IMDG) and air (IATA), consult the supplier's SDS §14.

MSDS vs SDS

MSDS vs SDS: is there a difference?

MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "propane MSDS" and a "propane SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →

Other compressed gases in our database

Compliance hub

From classification to SDS

The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →

GHS label maker

Build the label for propane

Pictograms, signal word and H-statements combined into a compliant label layout →

§ 16 · Sources

Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-07-27.

Frequently asked questions

Is an MSDS the same as an SDS?

In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "propane MSDS" is today issued as an SDS.

What GHS pictograms does propane require?

Under the harmonised EU classification (CLP Annex VI), propane carries GHS02 and GHS04 with the signal word "Danger". Hazard statements: H220. A supplier's SDS may add self-classified hazards on top of this harmonised minimum.

Where can I download an official propane SDS PDF?

From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.

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