Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.
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Safety data sheet reference · CAS 1330-20-7

Xylene SDS

also: xylene MSDS · safety data sheet · CAS 1330-20-7 · EC 202-422-2[1]203-396- · xylol · dimethylbenzene · mixed xylenes

Warning · Flam. Liq. 3 Category 4 · Skin Irrit. 2
Flame GHS02 Exclamation Mark GHS07

Official PDF from supplier

This page is a reference, not the legal document.

CAS number

1330-20-7

EC number

202-422-2[1]203-396-

CLP Annex VI index

601-022-00-9

§ 02 · Hazards identification

Harmonised EU classification

CLP Annex VI · Index 601-022-00-9. A supplier SDS may add self-classified hazards — this is the legal minimum.

H226 Flammable liquid and vapour. Flammable liquid — Category 3 (Flam. Liq. 3)
H312 Harmful in contact with skin. Acute toxicity, dermal — Category 4
H315 Causes skin irritation. Skin irritation — Category 2 (Skin Irrit. 2)
H332 Harmful if inhaled. Acute toxicity, inhalation — Category 4

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P241 Use explosion-proof equipment.
P242 Use non-sparking tools.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302 IF ON SKIN: wash with plenty of water.
P304 IF INHALED: remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER or doctor if you feel unwell.
P313 Get medical advice/attention.
P332 If skin irritation occurs: get medical advice/attention.
P352 Wash with plenty of water.
P403 Store in a well-ventilated place.

§ 07 · Handling and storage

Computed storage verdict

§ 09 · Physical and chemical properties

Measured properties

The full physical-property table (melting/boiling point, flash point, explosion limits, vapour pressure, density) is being populated for this substance from ECHA registration data and will appear here as it lands.

§ 10 · Stability and reactivity

Reactive group (CAMEO/NOAA): Hydrocarbons, Aromatic. Our database documents 6 incompatible and 6 caution reaction-partner groups for xylene — including which combinations release gas on contact. See the per-partner breakdown with gas release →

6

Incompatible

6

Caution

§ 13 · Disposal considerations

Dispose of waste and residues in accordance with local and national regulations — in the EU under the Waste Framework Directive 2008/98/EC. Never discharge to drains or municipal waste; hand contaminated packaging and unused product to an authorised waste-disposal company. The supplier's SDS section 13 lists the applicable waste codes for the specific product.

§ 14 · Transport information

Road transport — ADR 2025

UN number

UN 1307

Proper shipping name

XYLENES

Class · PG

3 · II

Classification code

F1

Transport category

2

ADR labels

3

Hazard ID (Kemler) / UN plate

33
1307

Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.

UN number

UN 1307

Proper shipping name

XYLENES

Class · PG

3 · III

Classification code

F1

Transport category

3

ADR labels

3

Hazard ID (Kemler) / UN plate

30
1307

Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.

Source: UN ADR 2025 (ECE/TRANS/352), Table A. Road (ADR) only — for sea (IMDG) and air (IATA), consult the supplier's SDS §14.

MSDS vs SDS

MSDS vs SDS: is there a difference?

MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "xylene MSDS" and a "xylene SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →

Other flammable liquids in our database

Compliance hub

From classification to SDS

The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →

GHS label maker

Build the label for xylene

Pictograms, signal word and H-statements combined into a compliant label layout →

§ 16 · Sources

Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-07-27.

Frequently asked questions

Is an MSDS the same as an SDS?

In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "xylene MSDS" is today issued as an SDS.

What GHS pictograms does xylene require?

Under the harmonised EU classification (CLP Annex VI), xylene carries GHS02 and GHS07 with the signal word "Warning". Hazard statements: H226, H332, H312, H315. A supplier's SDS may add self-classified hazards on top of this harmonised minimum.

What should xylene never be stored with?

Based on its storage class (Flammable liquids), xylene must not share storage with: Organic peroxides & self-reactives; Oxidizing acids; Oxidizers. Verify against the supplier's SDS sections 7 and 10 before finalising storage.

Where can I download an official xylene SDS PDF?

From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.

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