Safety data sheet reference · CAS 7664-39-3
Hydrofluoric acid SDS
also: hydrofluoric acid MSDS · safety data sheet · HF · CAS 7664-39-3 · EC 231-634-8 · hydrogen fluoride
Official PDF from supplier
This page is a reference, not the legal document.
CAS number
7664-39-3
EC number
231-634-8
CLP Annex VI index
009-002-00-6
Molecular formula
FH
Molar mass
20.006 g/mol
§ 02 · Hazards identification
Harmonised EU classification
CLP Annex VI · Index 009-002-00-6. A supplier SDS may add self-classified hazards — this is the legal minimum.
Precautionary statements
§ 07 · Handling and storage
Computed storage verdict
Derived from CLP Annex VI classification and CAMEO reactive-group data — not copied from a PDF.
⚠ Air-Reactive⚠ Water-Reactive
⛔ Never store with
↔ Keep separate
Full interactive verdict — reactions, gas release on contact, ADR forms →
§ 09 · Physical and chemical properties
Measured properties
The full physical-property table (melting/boiling point, flash point, explosion limits, vapour pressure, density) is being populated for this substance from ECHA registration data and will appear here as it lands.
§ 10 · Stability and reactivity
Reactive group (CAMEO/NOAA): Acids, Weak, Fluoride Salts, Soluble, Water and Aqueous Solutions. Our database documents 48 incompatible and 65 caution reaction-partner groups for hydrofluoric acid — including which combinations release gas on contact. See the per-partner breakdown with gas release →
48
Incompatible
65
Caution
§ 13 · Disposal considerations
Dispose of waste and residues in accordance with local and national regulations — in the EU under the Waste Framework Directive 2008/98/EC. Never discharge to drains or municipal waste; hand contaminated packaging and unused product to an authorised waste-disposal company. The supplier's SDS section 13 lists the applicable waste codes for the specific product.
§ 14 · Transport information
Road transport — ADR 2025
UN number
UN 1052
Proper shipping name
HYDROGEN FLUORIDE, ANHYDROUS
Class · PG
8 · I
Classification code
CT1
Transport category
1
ADR labels
8, 6.1
Hazard ID (Kemler) / UN plate
Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.
Source: UN ADR 2025 (ECE/TRANS/352), Table A. Road (ADR) only — for sea (IMDG) and air (IATA), consult the supplier's SDS §14.
MSDS vs SDS
MSDS vs SDS: is there a difference?
MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "hydrofluoric acid MSDS" and a "hydrofluoric acid SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →
Other mineral acids in our database
- 1,4-dihydroxybenzene; hydroquinone; quinol 123-31-9
- 2,3,4,6-tetrachlorophenol 58-90-2
- 2,4-dichlorophenol 120-83-2
- 2,4,5-trichlorophenol 95-95-4
- 2,4,6-trichlorophenol 88-06-2
- 3-aminobenzene sulphonic acid; metanilic acid 121-47-1
- aluminium chloride, anhydrous 7446-70-0
- antimony pentachloride 7647-18-9
Compliance hub
From classification to SDS
The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →
GHS label maker
Build the label for hydrofluoric acid
Pictograms, signal word and H-statements combined into a compliant label layout →
§ 16 · Sources
- Classification: Regulation (EC) No 1272/2008 (CLP), Annex VI
- Transport: UN ADR 2025 (UNECE), Table A
- Reactivity: NOAA CAMEO Chemicals reactive-group matrix (public domain)
- Physical properties: CAMEO Chemicals (NOAA, public domain) — per-value source references stored in the database
- Substance data: PubChem · ECHA
Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-07-27.
Frequently asked questions
Is an MSDS the same as an SDS?
In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "hydrofluoric acid MSDS" is today issued as an SDS.
What GHS pictograms does hydrofluoric acid require?
Under the harmonised EU classification (CLP Annex VI), hydrofluoric acid carries GHS05 and GHS06 with the signal word "Danger". Hazard statements: H310, H330, H300, H314. A supplier's SDS may add self-classified hazards on top of this harmonised minimum.
What should hydrofluoric acid never be stored with?
Based on its storage classes (Mineral acids, Acute toxics), hydrofluoric acid must not share storage with: Bases; Cyanides & sulfides; Organic peroxides & self-reactives; Oxidizing acids; Oxidizers; Reactive metals; Water-reactives. Verify against the supplier's SDS sections 7 and 10 before finalising storage.
Where can I download an official hydrofluoric acid SDS PDF?
From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.