Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.
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Safety data sheet reference · CAS 127-18-4

Tetrachloroethylene SDS

also: tetrachloroethylene MSDS · safety data sheet · CAS 127-18-4 · EC 204-825-9 · perchloroethylene · perc · PCE

Warning Carc. 2 Category 2 UN 1897 · ADR 6.1 · PG III
Health Hazard GHS08 Environmental Hazard GHS09

Official PDF from supplier

This page is a reference, not the legal document.

CAS number

127-18-4

EC number

204-825-9

CLP Annex VI index

602-028-00-4

Molecular formula

C2Cl4

Molar mass

165.8 g/mol

§ 02 · Hazards identification

Harmonised EU classification

CLP Annex VI · Index 602-028-00-4. A supplier SDS may add self-classified hazards — this is the legal minimum.

H351 Suspected of causing cancer. Carcinogenicity — Category 2 (Carc. 2)
H411 Toxic to aquatic life with long lasting effects. Aquatic chronic — Category 2

Precautionary statements

P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308 IF exposed or concerned: get medical advice/attention.
P313 Get medical advice/attention.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulations.

§ 07 · Handling and storage

Computed storage verdict

No storage segregation conflicts documented

Derived from CLP Annex VI classification and CAMEO reactive-group data — not copied from a PDF.

Full interactive verdict — reactions, gas release on contact, ADR forms →

§ 09 · Physical and chemical properties

Measured properties

Melting point -18.9 °C
Boiling point 121.1 °C
Relative density (water = 1) 1.63

Source: CAMEO Chemicals (NOAA, public domain); per-value source references stored in the database.

§ 10 · Stability and reactivity

Reactive group (CAMEO/NOAA): Halogenated Organic Compounds, Hydrocarbons, Aliphatic Unsaturated. Our database documents 30 incompatible and 21 caution reaction-partner groups for tetrachloroethylene — including which combinations release gas on contact. See the per-partner breakdown with gas release →

30

Incompatible

21

Caution

§ 13 · Disposal considerations

Dispose of waste and residues in accordance with local and national regulations — in the EU under the Waste Framework Directive 2008/98/EC. Never discharge to drains or municipal waste; hand contaminated packaging and unused product to an authorised waste-disposal company. The supplier's SDS section 13 lists the applicable waste codes for the specific product.

§ 14 · Transport information

Road transport — ADR 2025

UN number

UN 1897

Proper shipping name

TETRACHLOROETHYLENE

Class · PG

6.1 · III

Classification code

T1

Transport category

2

ADR labels

6.1

Hazard ID (Kemler) / UN plate

60
1897

Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.

Source: UN ADR 2025 (ECE/TRANS/352), Table A. Road (ADR) only — for sea (IMDG) and air (IATA), consult the supplier's SDS §14.

MSDS vs SDS

MSDS vs SDS: is there a difference?

MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "tetrachloroethylene MSDS" and a "tetrachloroethylene SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →

Compliance hub

From classification to SDS

The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →

GHS label maker

Build the label for tetrachloroethylene

Pictograms, signal word and H-statements combined into a compliant label layout →

§ 16 · Sources

Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-07-27.

Frequently asked questions

Is an MSDS the same as an SDS?

In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "tetrachloroethylene MSDS" is today issued as an SDS.

What GHS pictograms does tetrachloroethylene require?

Under the harmonised EU classification (CLP Annex VI), tetrachloroethylene carries GHS08 and GHS09 with the signal word "Warning". Hazard statements: H351, H411. A supplier's SDS may add self-classified hazards on top of this harmonised minimum.

Where can I download an official tetrachloroethylene SDS PDF?

From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.

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