Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.
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Safety data sheet reference · CAS 111-30-8

Glutaraldehyde SDS

also: glutaraldehyde MSDS · safety data sheet · CAS 111-30-8 · EC 203-856-5 · glutaral

Danger Category 1–2 · Acute Tox. 3 · STOT SE 3 · +3 Aquatic Acute 1 · Category 2
Corrosion GHS05 Skull and Crossbones GHS06 Health Hazard GHS08 Environmental Hazard GHS09

Official PDF from supplier

This page is a reference, not the legal document.

CAS number

111-30-8

EC number

203-856-5

CLP Annex VI index

605-022-00-X

Molecular formula

C5H8O2

Molar mass

100.12 g/mol

§ 02 · Hazards identification

Harmonised EU classification

CLP Annex VI · Index 605-022-00-X. A supplier SDS may add self-classified hazards — this is the legal minimum.

H301 Toxic if swallowed. Acute toxicity, oral — Category 3 (Acute Tox. 3)
H314 Causes severe skin burns and eye damage. Skin corrosion — Category 1 (Skin Corr. 1)
H317 May cause an allergic skin reaction. Skin sensitiser — Category 1 (Skin Sens. 1)
H330 Fatal if inhaled. Acute toxicity, inhalation — Category 1–2
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Respiratory sensitiser — Category 1 (Resp. Sens. 1)
H335 May cause respiratory irritation. Respiratory irritation — STOT SE 3
H400 Very toxic to aquatic life. Hazardous to aquatic environment, acute — Category 1 (Aquatic Acute 1)
H411 Toxic to aquatic life with long lasting effects. Aquatic chronic — Category 2

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 IF SWALLOWED: call a POISON CENTER or doctor if you feel unwell.
P304 IF INHALED: remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER or doctor.
P313 Get medical advice/attention.
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P333 If skin irritation or rash occurs: get medical advice/attention.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulations.

§ 07 · Handling and storage

Computed storage verdict

§ 09 · Physical and chemical properties

Measured properties

The full physical-property table (melting/boiling point, flash point, explosion limits, vapour pressure, density) is being populated for this substance from ECHA registration data and will appear here as it lands.

§ 10 · Stability and reactivity

Reactive group (CAMEO/NOAA): Aldehydes, Polymerizable Compounds, Water and Aqueous Solutions. Our database documents 71 incompatible and 76 caution reaction-partner groups for glutaraldehyde — including which combinations release gas on contact. See the per-partner breakdown with gas release →

71

Incompatible

76

Caution

§ 13 · Disposal considerations

Dispose of waste and residues in accordance with local and national regulations — in the EU under the Waste Framework Directive 2008/98/EC. Never discharge to drains or municipal waste; hand contaminated packaging and unused product to an authorised waste-disposal company. The supplier's SDS section 13 lists the applicable waste codes for the specific product.

MSDS vs SDS

MSDS vs SDS: is there a difference?

MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "glutaraldehyde MSDS" and a "glutaraldehyde SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →

Other acute toxics in our database

Compliance hub

From classification to SDS

The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →

GHS label maker

Build the label for glutaraldehyde

Pictograms, signal word and H-statements combined into a compliant label layout →

§ 16 · Sources

Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-07-27.

Frequently asked questions

Is an MSDS the same as an SDS?

In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "glutaraldehyde MSDS" is today issued as an SDS.

What GHS pictograms does glutaraldehyde require?

Under the harmonised EU classification (CLP Annex VI), glutaraldehyde carries GHS05 and GHS06 and GHS08 and GHS09 with the signal word "Danger". Hazard statements: H330, H301, H335, H314, H334, H317, H400, H411. A supplier's SDS may add self-classified hazards on top of this harmonised minimum.

Where can I download an official glutaraldehyde SDS PDF?

From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.

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