Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.
GHS Ecosystem: GHS Symbols → Hazard Classification ▶ You are on GHS Pictograms GHS Labels

Safety data sheet reference · CAS 79-06-1

Acrylamide SDS

also: acrylamide MSDS · safety data sheet · CAS 79-06-1 · EC 201-173-7

Danger Carc. 1 · Muta. 1 · Acute Tox. 3 · +5
Skull and Crossbones GHS06 Health Hazard GHS08

Official PDF from supplier

This page is a reference, not the legal document.

CAS number

79-06-1

EC number

201-173-7

CLP Annex VI index

616-003-00-0

Molecular formula

C3H5NO

Molar mass

71.08 g/mol

§ 02 · Hazards identification

Harmonised EU classification

CLP Annex VI · Index 616-003-00-0. A supplier SDS may add self-classified hazards — this is the legal minimum.

H301 Toxic if swallowed. Acute toxicity, oral — Category 3 (Acute Tox. 3)
H312 Harmful in contact with skin. Acute toxicity, dermal — Category 4
H315 Causes skin irritation. Skin irritation — Category 2 (Skin Irrit. 2)
H317 May cause an allergic skin reaction. Skin sensitiser — Category 1 (Skin Sens. 1)
H319 Causes serious eye irritation. Eye irritation — Category 2 (Eye Irrit. 2)
H332 Harmful if inhaled. Acute toxicity, inhalation — Category 4
H340 May cause genetic defects. Germ cell mutagenicity — Category 1 (Muta. 1)
H350 May cause cancer. Carcinogenicity — Category 1 (Carc. 1)
H372 Causes damage to organs through prolonged or repeated exposure. STOT repeated exposure — Category 1 (STOT RE 1)

Precautionary statements

P201 Obtain special instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 IF SWALLOWED: call a POISON CENTER or doctor if you feel unwell.
P302 IF ON SKIN: wash with plenty of water.
P304 IF INHALED: remove person to fresh air and keep comfortable for breathing.
P305 IF IN EYES: rinse cautiously with water for several minutes.
P308 IF exposed or concerned: get medical advice/attention.
P310 Immediately call a POISON CENTER or doctor.
P312 Call a POISON CENTER or doctor if you feel unwell.
P313 Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P330 Rinse mouth.
P332 If skin irritation occurs: get medical advice/attention.
P333 If skin irritation or rash occurs: get medical advice/attention.
P337 If eye irritation persists: get medical advice/attention.
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P352 Wash with plenty of water.

§ 07 · Handling and storage

Computed storage verdict

§ 09 · Physical and chemical properties

Measured properties

Fire-relevant values first — flash point and explosion limits decide the storage and ventilation regime.

Flash point

138 °C

Autoignition

240 °C

Melting point 84.4 °C
Relative density (water = 1) 1.122

Source: CAMEO Chemicals (NOAA, public domain); per-value source references stored in the database.

§ 10 · Stability and reactivity

Reactive group (CAMEO/NOAA): Acrylates and Acrylic Acids, Amides and Imides, Polymerizable Compounds, Water and Aqueous Solutions. Our database documents 79 incompatible and 123 caution reaction-partner groups for acrylamide — including which combinations release gas on contact. See the per-partner breakdown with gas release →

79

Incompatible

123

Caution

§ 13 · Disposal considerations

Dispose of waste and residues in accordance with local and national regulations — in the EU under the Waste Framework Directive 2008/98/EC. Never discharge to drains or municipal waste; hand contaminated packaging and unused product to an authorised waste-disposal company. The supplier's SDS section 13 lists the applicable waste codes for the specific product.

§ 14 · Transport information

Road transport — ADR 2025

UN number

UN 2074

Proper shipping name

ACRYLAMIDE, SOLID

Class · PG

6.1 · III

Classification code

T2

Transport category

2

ADR labels

6.1

Hazard ID (Kemler) / UN plate

60
2074

Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.

UN number

UN 3426

Proper shipping name

ACRYLAMIDE SOLUTION

Class · PG

6.1 · III

Classification code

T1

Transport category

2

ADR labels

6.1

Hazard ID (Kemler) / UN plate

60
3426

Top: hazard identification number (Kemler). Bottom: UN number — as carried on the orange plate of the transport unit.

Source: UN ADR 2025 (ECE/TRANS/352), Table A. Road (ADR) only — for sea (IMDG) and air (IATA), consult the supplier's SDS §14.

MSDS vs SDS

MSDS vs SDS: is there a difference?

MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "acrylamide MSDS" and a "acrylamide SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →

Other acute toxics in our database

Compliance hub

From classification to SDS

The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →

GHS label maker

Build the label for acrylamide

Pictograms, signal word and H-statements combined into a compliant label layout →

§ 16 · Sources

Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-07-27.

Frequently asked questions

Is an MSDS the same as an SDS?

In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "acrylamide MSDS" is today issued as an SDS.

What GHS pictograms does acrylamide require?

Under the harmonised EU classification (CLP Annex VI), acrylamide carries GHS06 and GHS08 with the signal word "Danger". Hazard statements: H350, H340, H361f, H301, H332, H312, H372, H315, H319, H317. A supplier's SDS may add self-classified hazards on top of this harmonised minimum.

Where can I download an official acrylamide SDS PDF?

From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.

Get the free GHS / CLP / OSHA deadline calendar

Verified 2026–2029 compliance dates in one PDF — plus alerts when the rules change.