Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.
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Safety data sheet reference · CAS 7758-98-7

Copper sulfate SDS

also: copper sulfate MSDS · safety data sheet · CuSO4 · CAS 7758-98-7 · EC 231-847-6 · bluestone · blue vitriol

Warning Acute Tox. 4 · Skin Irrit. 2 · Eye Irrit. 2 Aquatic Acute 1 · Aquatic Chronic 1
Exclamation Mark GHS07 Environmental Hazard GHS09

Official PDF from supplier

This page is a reference, not the legal document.

CAS number

7758-98-7

EC number

231-847-6

CLP Annex VI index

029-004-00-0

Molecular formula

CuO4S

Molar mass

159.61 g/mol

§ 02 · Hazards identification

Harmonised EU classification

CLP Annex VI · Index 029-004-00-0. A supplier SDS may add self-classified hazards — this is the legal minimum.

H302 Harmful if swallowed. Acute toxicity, oral — Category 4 (Acute Tox. 4)
H315 Causes skin irritation. Skin irritation — Category 2 (Skin Irrit. 2)
H319 Causes serious eye irritation. Eye irritation — Category 2 (Eye Irrit. 2)
H400 Very toxic to aquatic life. Hazardous to aquatic environment, acute — Category 1 (Aquatic Acute 1)
H410 Very toxic to aquatic life with long lasting effects. Hazardous to aquatic environment, chronic — Category 1 (Aquatic Chronic 1)

Precautionary statements

P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 IF SWALLOWED: call a POISON CENTER or doctor if you feel unwell.
P302 IF ON SKIN: wash with plenty of water.
P305 IF IN EYES: rinse cautiously with water for several minutes.
P312 Call a POISON CENTER or doctor if you feel unwell.
P313 Get medical advice/attention.
P330 Rinse mouth.
P332 If skin irritation occurs: get medical advice/attention.
P337 If eye irritation persists: get medical advice/attention.
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P352 Wash with plenty of water.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulations.

§ 07 · Handling and storage

Computed storage verdict

No storage segregation conflicts documented

Derived from CLP Annex VI classification and CAMEO reactive-group data — not copied from a PDF.

Full interactive verdict — reactions, gas release on contact, ADR forms →

§ 09 · Physical and chemical properties

Measured properties

Relative density (water = 1) 2.29

Source: CAMEO Chemicals (NOAA, public domain); per-value source references stored in the database.

§ 10 · Stability and reactivity

Reactive group (CAMEO/NOAA): Salts, Acidic. Our database documents 23 incompatible and 22 caution reaction-partner groups for copper sulfate — including which combinations release gas on contact. See the per-partner breakdown with gas release →

23

Incompatible

22

Caution

§ 13 · Disposal considerations

Dispose of waste and residues in accordance with local and national regulations — in the EU under the Waste Framework Directive 2008/98/EC. Never discharge to drains or municipal waste; hand contaminated packaging and unused product to an authorised waste-disposal company. The supplier's SDS section 13 lists the applicable waste codes for the specific product.

MSDS vs SDS

MSDS vs SDS: is there a difference?

MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "copper sulfate MSDS" and a "copper sulfate SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →

Compliance hub

From classification to SDS

The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →

GHS label maker

Build the label for copper sulfate

Pictograms, signal word and H-statements combined into a compliant label layout →

§ 16 · Sources

Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-07-27.

Frequently asked questions

Is an MSDS the same as an SDS?

In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "copper sulfate MSDS" is today issued as an SDS.

What GHS pictograms does copper sulfate require?

Under the harmonised EU classification (CLP Annex VI), copper sulfate carries GHS07 and GHS09 with the signal word "Warning". Hazard statements: H302, H315, H319, H400, H410. A supplier's SDS may add self-classified hazards on top of this harmonised minimum.

Where can I download an official copper sulfate SDS PDF?

From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.

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