Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Diethylene glycol dinitrate

Diethylene glycol dinitrate is a liquid.

CAS 693-21-0 C4H8N2O7 196.12 g/mol Danger

01 · Identification

What Diethylene glycol dinitrate is

Diethylene glycol dinitrate is a liquid. Its molecular formula is C4H8N2O7 and its molecular weight is 196.12 g/mol. It boils at 161 °C, melts at -11.3 °C.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 4th degree.

CAS number693-21-0
EC number211-745-8
Index number603-033-00-4
Molecular formulaC4H8N2O7
Molecular weight196.12 g/mol
Chemical class Flammable agents - 4th degree

Other names for Diethylene glycol dinitrate

  • oxydiethylene dinitrate
  • digol dinitrate

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to Diethylene glycol dinitrate
CodeHazard statement
H310 Fatal in contact with skin.
H330 Fatal if inhaled.
H300 Fatal if swallowed.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H412 Harmful to aquatic life with long lasting effects.
H200 Unstable explosives.

Precautionary statements: P210, P260, P270, P271, P273, P280, P301, P302, P304, P310, P314, P330, P352, P501

This page lists only the codes assigned to Diethylene glycol…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

03 · Physical and chemical properties

Diethylene glycol dinitrate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 161 °C (321.8 °F) HSDB
44 °C (111.2 °F) at 0.01 mmHg (reduced pressure) HSDB
139 °C (282.2 °F) at 6.75056 mmHg (reduced pressure) ICSC
Melting point -11.3 °C (11.7 °F) HSDB
2 °C (35.6 °F) ICSC
Density 1.377 g/cm³ at 25 °C HSDB
Solubility Slightly soluble in alcohol; soluble in ether HSDB
In water, 3.9X10+3 mg/L at 25 °C at 25 °C HSDB
Vapor pressure 0.0038 mmHg at 20 °C ICSC
0.0059 mmHg at 25 °C HSDB
0.0059 mmHg Haz-Map
Lower explosive limit (LEL) A dangerous explosive sensitive to heat, shock, and vibration. HSDB
Vapor density 6.76 (air = 1) HSDB
Odor threshold About 680 mg/L in water HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Fire and explosion

Fire and explosion behaviour of Diethylene glycol…

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Fire and explosion

Diethyleneglycol dinitrate ... is a liquid which is an extremely sensitive explosive if not properly desensitized with a phlegmatizer ... Under prolonged exposure to heat or fire or from sudden shock /it/ can explode. /Diethylenegylcol dinitrate, desensitized/

Source: HSDB

05 · Handling and storage

Storing and handling Diethylene glycol dinitrate

Storage conditions

Fireproof. Store in separate building. Separated from acids, food and feedstuffs . Cool. Well closed.

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

Can react vigorously with oxidizing or reducing materials.

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

Nitroorganics, such as DIETHYLENE GLYCOL DINITRATE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Diethylene glycol… in the storage compatibility matrix →

Safety Data Sheet

Getting an SDS for Diethylene glycol…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Diethylene glycol… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

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