Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Transport reference

UN 2821 — Phenol solution

Table A of ADR 2025 and the 49 CFR 172.101 Hazardous Materials Table for this number, kept side by side and never merged, plus the CLP label elements of the substances that ship under it.

ADR class 6.1 49 CFR 6.1 PG II, III Hazard ID 60 1 linked substance
ADR orange-coloured plate: hazard identification number 60 above UN 2821 60 2821

The two tables are never merged. The same UN number can carry a different packing group, a different proper shipping name and entirely different special provisions in each system. Every value below sits under the name of the jurisdiction it comes from.

01 · Two jurisdictions

UN 2821 in ADR 2025 and in 49 CFR 172.101

The two systems differ for this number on 1 of 5 fields. Special provisions are deliberately absent from this comparison: identical code numbers mean different things in the two systems.

Field ADR 2025 Table A, Chapter 3.2 49 CFR 172.101 eCFR 2026-08-03
Proper shipping name PHENOL SOLUTION Phenol solutions
Class or division 6.1 6.1
Packing group II, III II, III
Label codes 6.1 6.1
Rows in the table 2 2

Sources: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE) · 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03

02 · ADR 2025

UN 2821 in Table A of ADR 2025

2 separate rows in Table A of Chapter 3.2. They are not interchangeable: the packing group follows from the properties of the consignment, and each row carries its own transport category — that is a different multiplier in the 1.1.3.6 calculation.

Proper shipping name (3.1.2) Class Classification code PG Labels Transport category Hazard ID
PHENOL SOLUTION 6.1 T1 II 6.1 2 60
PHENOL SOLUTION 6.1 T1 III 6.1 2 60

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 6.1 is “Toxic substances” (ADR 2.1.1.1).

Transport category and the 1 000-point exemption

Column (15) of Table A decides whether a load stays under the exemption of ADR 1.1.3.6. Quantities of different categories are added with the multipliers below, and the sum must not exceed 1 000.

Category Max total quantity per transport unit Multiplier in 1.1.3.6.4 What it means
2 333 × 3 Packing group II and the listed classes.

Source: ADR 2025, 1.1.3.6.3 and 1.1.3.6.4 · ECE/TRANS/352 Vol. I (UNECE).

Carriage provisions — CV codes

CV13 Any leaked/spilled substance must be cleaned up before the unit is reused.
CV28 Must be segregated from foodstuffs, other consumables and animal feed (7.5.4). · relevant to segregation on the vehicle

Source: ADR 2025, 7.5.11 · ECE/TRANS/352 Vol. II (UNECE)

Not imported and therefore not shown for this number: limited quantities (column 7a), excepted quantities (7b), packing instructions (8), tank codes (10–13) and the tunnel restriction code (15). An empty section is more honest than borrowed text.

UN 2821 in the 49 CFR 172.101 Hazardous Materials Table

2 separate rows in the Hazardous Materials Table. Where the rows differ only by the symbol in column (1), that symbol is what tells them apart — “D” is domestic-only, “I” is international.

Symbols (1) Proper shipping name (2) Class (3) PG (5) Labels (6) Packaging (8) Quantity limits (9) Vessel stowage (10)
Phenol solutions 6.1 II 6.1 §173.153 · §173.202 · §173.243 5 L passenger
60 L cargo
A
Phenol solutions 6.1 III 6.1 §173.153 · §173.203 · §173.241 60 L passenger
220 L cargo
A

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 6.1 is “Poisonous materials” (49 CFR 173.2). Packaging cells are section references into 49 CFR part 173: exceptions, non-bulk, bulk. Handling codes in column 10B are defined in 49 CFR 176.84, which is not part of our import — the numbers are shown as printed in the table.

Vessel stowage categories on this entry

A May be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel.

Source: 49 CFR 172.101(k) · eCFR, revision 2026-08-03

Special provisions — 49 CFR 172.102

Codes from column (7) of the Hazardous Materials Table, with the text of § 172.102. These are United States provisions only and have nothing to do with the ADR codes above, even where the number is identical.

IB2 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
IB3 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2).
T4 Portable tank instruction. Minimum test pressure: 2.65 bar; minimum shell thickness (reference steel): § 178.274(d)(2); pressure-relief requirements: Normal; bottom opening requirements: § 178.275(d)(3). See 49 CFR 172.102(c)(7)(ii), Table of Portable Tank T Codes T1-T22.
T7 Portable tank instruction. Minimum test pressure: 4 bar; minimum shell thickness (reference steel): § 178.274(d)(2); pressure-relief requirements: Normal; bottom opening requirements: § 178.275(d)(3). See 49 CFR 172.102(c)(7)(ii), Table of Portable Tank T Codes T1-T22.
TP1 The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following:

Source: 49 CFR 172.102 special provisions · eCFR, revision 2026-08-03

04 · Orange plate

The orange-coloured plate for UN 2821

The upper half of the plate carries the hazard identification number, the lower half the UN number. Dimensions follow ADR 5.3.2.2.1: 400 × 300 mm, black border and dividing line 15 mm, figures 100 mm high.

ADR orange-coloured plate: hazard identification number 60 above UN 2821 60 2821

60 — toxic or slightly toxic substance.

6 Toxicity or risk of infection
0 No further hazard — the first figure alone describes the hazard adequately

Source: ADR 2025, 5.3.2.3 · ECE/TRANS/352 Vol. II (UNECE). The tunnel restriction code of column (15) is a different value and is not part of our import.

05 · Substances

Substances shipped under UN 2821

Linked by CAS number, never by name: a name match once produced “acetone cyanohydrin” for acetone, and a wrong link here would be a wrong classification. Each entry opens its own reference page with the CLP classification and label elements.

Full 16-section safety data sheets: Phenol

06 · The label side

What UN 2821 looks like on a workplace label

The tables above are the transport classification. This is the other half of the same material: the CLP label elements of the substances linked to this number — what actually goes on the drum once it has been delivered. Transport marks and supply labels answer different regulations and do not replace one another.

Signal word across the linked substances: Danger

Hazard statements on the substances under UN 2821

H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H341 Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

Source: harmonised classification, EU CLP Annex VI. Transport classification and supply classification are decided under different rules and do not have to agree.

UN 2821 — frequently asked questions

What is UN 2821?

UN 2821 is the United Nations number for Phenol solution. Under ADR 2025 it is assigned to class 6.1 (toxic substances), classification code T1.

What packing group is UN 2821?

Table A of ADR 2025 lists UN 2821 under 2 packing groups — II, III — as separate rows. The packing group follows from the properties of the specific consignment; it is not interchangeable, and each row carries its own transport category.

Is UN 2821 classified the same way in the United States and in Europe?

No. For UN 2821 the two tables differ on proper shipping name. Each panel on this page shows its own source; values from one system must not be carried over into the other.

What is the hazard identification number for UN 2821?

The orange-coloured plate for UN 2821 carries the hazard identification number 60 above the UN number. Under ADR 5.3.2.3.2 that number means: toxic or slightly toxic substance.

What is the transport category of UN 2821?

Column (15) of Table A puts UN 2821 in transport category 2. Under ADR 1.1.3.6.3 the maximum total quantity per transport unit for that category is 333.

Which substances ship under UN 2821?

We hold 1 substance linked to UN 2821 by CAS number, 1 of which also has a full safety data sheet on this site. Each one has its own reference page with the CLP classification, GHS pictograms and hazard statements that apply on the label — the workplace side of the same material.

Need the plate, the labels or the placards printed?

The orange plate above is a physical article, and so are the class labels in column (5). Our sister site GHSLabels.com covers printing and suppliers. For the workplace label of the same material, use the GHS label constructor, and browse other numbers in the UN number reference.

Reference aid only. Values are reproduced from ADR 2025 and the 49 CFR 172.101 table as published; the consignor remains responsible for the classification of a specific consignment. Always verify against the current published regulation and the supplier's safety data sheet.

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