Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

1-chloro-2,3-epoxypropane

1-chloro-2,3-epoxypropane is a colorless liquid with an odor is sweet, pungent or chloroform-like generally perceived as a slightly.

CAS 106-89-8 C3H5ClO 92.52 g/mol Danger

01 · Identification

What 1-chloro-2,3-epoxypropane is

1-chloro-2,3-epoxypropane is a colorless liquid with an odor is sweet, pungent or chloroform-like generally perceived as a slightly. Its molecular formula is C3H5ClO and its molecular weight is 92.52 g/mol. It boils at 118 °C, melts at -25.6 °C, is miscible with water.

Under the GHS it carries the signal word Danger. It is classed as hazardous Air Pollutants (HAPs).

CAS number106-89-8
EC number203-439-8
Index number603-026-00-6
Molecular formulaC3H5ClO
Molecular weight92.52 g/mol
Chemical class Hazardous Air Pollutants (HAPs)

Other names for 1-chloro-2,3-epoxypropane

  • epichlorhydrin

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to 1-chloro-2,3-epoxypropane
CodeHazard statement
H226 Flammable liquid and vapour.
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H331 Toxic if inhaled.
H311 Toxic in contact with skin.
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.

Precautionary statements: P201, P210, P233, P241, P242, P260, P261, P270, P271, P272, P280, P301, P302, P304, P308, P310, P313, P330, P331, P333, P352, P403

03 · Physical and chemical properties

1-chloro-2,3-epoxypropane properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 117.9 °C (244.2 °F) HSDB
116.67 °C (242 °F) NIOSH
116.5 °C (241.7 °F) at 760 mmHg CAMEO
Melting point -25.6 °C (-14.1 °F) HSDB
-47.78 °C (-54 °F) NIOSH
-48 °C (-54.4 °F) ICSC
Density 1.18 g/cm³ NIOSH
1.2 g/cm³ ICSC
1.175 g/cm³ at 25 °C HSDB
Solubility Miscible with most organic solvents HSDB
Miscible with alcohol, ether, chloroform, trichloroethylene, carbon tetrachloride; immiscible with petroleum hydrocarbons. HSDB
In water, 6.59X10+4 mg/L at 25 °C at 25 °C HSDB
Vapor pressure 13 mmHg NIOSH
12.001 mmHg at 20 °C ICSC
16.4 mmHg at 25 °C HSDB
Flash point 31.11 °C (88 °F) HSDB
33.89 °C (93 °F) NIOSH
Autoignition temperature 411.11 °C (772 °F) HSDB
385 °C (725 °F) ICSC
Lower explosive limit (LEL) 3.8 % by volume HSDB
Upper explosive limit (UEL) 21 % by volume HSDB
Vapor density 3.29 (air = 1) HSDB
3.2 (air = 1) ICSC
Odor threshold Sensory perception studies indicate that mean threshold for odor recognition is approximately 10 ppm ... @ 25 ppm it is recognized by majority of persons. HSDB
Human Odor Perception: non perception 0.2 mg/cu m; perception 0.3 mg/cu m HSDB
Odor Threshold Low: 0.08 [ppm] Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling 1-chloro-2,3-epoxypropane

Storage conditions

Separate from acids, alkalies, salts, water, and oxidizers. Store in a cool, dry, well-ventilated location. Inside storage should be in a standard flammable liquids storage warehouse, room, or cabinet.

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

Strong oxidizers, strong acids, certain salts, caustics, zinc, aluminum, water [Note: May polymerize in presence of strong acids and bases particularly when hot.].

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

1-CHLORO-2,3-EPOXYPROPANE may polymerize exothermically if heated or contaminated. Reacts explosively with aniline. Ignites on contact with potassium tert-butoxide. Reacts with trichloroethylene to give the explosive dichloroacetylene. Violent reaction with sulfuric acid or isopropylamine. Exothermic polymerization on contact with strong acids or bases, zinc, aluminum, aluminum chloride, iron, ferric chloride [Sax, 9th ed., 1996, p. 1469].

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 1-chloro-2,3-epoxypropane in the storage compatibility matrix →

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