Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

Build a label

Transport reference

UN 2692 — Boron tribromide

Table A of ADR 2025 and the 49 CFR 172.101 Hazardous Materials Table for this number, kept side by side and never merged, plus the CLP label elements of the substances that ship under it.

ADR class 8 49 CFR 8 PG I Hazard ID X88 1 linked substance
ADR orange-coloured plate: hazard identification number X88 above UN 2692 X88 2692

The two tables are never merged. The same UN number can carry a different packing group, a different proper shipping name and entirely different special provisions in each system. Every value below sits under the name of the jurisdiction it comes from.

01 · Two jurisdictions

UN 2692 in ADR 2025 and in 49 CFR 172.101

The two systems differ for this number on 1 of 5 fields. Special provisions are deliberately absent from this comparison: identical code numbers mean different things in the two systems.

Field ADR 2025 Table A, Chapter 3.2 49 CFR 172.101 eCFR 2026-08-03
Proper shipping name BORON TRIBROMIDE Boron tribromide
Class or division 8 8
Packing group I I
Label codes 8 8, 6.1
Rows in the table 1 1

Sources: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE) · 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03

02 · ADR 2025

UN 2692 in Table A of ADR 2025

One row in Table A of Chapter 3.2. Every value below comes from that row.

Proper shipping name (3.1.2) Class Classification code PG Labels Transport category Hazard ID
BORON TRIBROMIDE 8 C1 I 8 1 X88

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 8 is “Corrosive substances” (ADR 2.1.1.1).

Transport category and the 1 000-point exemption

Column (15) of Table A decides whether a load stays under the exemption of ADR 1.1.3.6. Quantities of different categories are added with the multipliers below, and the sum must not exceed 1 000.

Category Max total quantity per transport unit Multiplier in 1.1.3.6.4 What it means
1 20 × 50 Packing group I and the listed classes — the exemption runs out after 20 kg or litres per transport unit.

Source: ADR 2025, 1.1.3.6.3 and 1.1.3.6.4 · ECE/TRANS/352 Vol. I (UNECE).

Not imported and therefore not shown for this number: limited quantities (column 7a), excepted quantities (7b), packing instructions (8), tank codes (10–13) and the tunnel restriction code (15). An empty section is more honest than borrowed text.

UN 2692 in the 49 CFR 172.101 Hazardous Materials Table

One row in the Hazardous Materials Table.

Symbols (1) Proper shipping name (2) Class (3) PG (5) Labels (6) Packaging (8) Quantity limits (9) Vessel stowage (10)
+ Boron tribromide 8 I 8, 6.1 §173.None · §173.227 · §173.244 Forbidden passenger
Forbidden cargo
C · 12, 25, 53, 58

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 8 is “Corrosive material” (49 CFR 173.2). Packaging cells are section references into 49 CFR part 173: exceptions, non-bulk, bulk. Handling codes in column 10B are defined in 49 CFR 176.84, which is not part of our import — the numbers are shown as printed in the table.

What the column (1) symbols mean

+ Fixed entry. The plus sign fixes the proper shipping name, hazard class and packing group for that entry without regard to whether the material meets the definition of that class, packing group or any other hazard class definition.

Source: 49 CFR 172.101(b) · eCFR, revision 2026-08-03

Vessel stowage categories on this entry

C Must be stowed “on deck only” on a cargo vessel or on a passenger vessel.

Source: 49 CFR 172.101(k) · eCFR, revision 2026-08-03

Special provisions — 49 CFR 172.102

Codes from column (7) of the Hazardous Materials Table, with the text of § 172.102. These are United States provisions only and have nothing to do with the ADR codes above, even where the number is identical.

2 This material is poisonous by inhalation (see § 171.8 of this subchapter) in Hazard Zone B (see § 173.116(a) or § 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.
B14 Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials must not promote corrosion to steel when wet.
B32 MC 312, MC 330, MC 331, DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of § 173.24b(b) of this subchapter. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 6.35 mm (0.250 inch) or the thickness required for a tank with a design pressure at least equal to 1.3 times the vapor pressure of the lading at 46 °C (115 °F). In addition, MC 312 and DOT 412 cargo tank motor vehicles must: a. Be ASME Code (U) stamped for 100% radiography of all pressure-retaining welds; b. Have accident damage protection which conforms with § 178.345-8 of this subchapter; c. Have a MAWP or design pressure of at least 87 psig; and d. Have a bolted manway cover.
B9 Bottom outlets are not authorized.
N34 Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.
T20 Portable tank instruction. Minimum test pressure: 10 bar; minimum shell thickness (reference steel): 8 mm; pressure-relief requirements: § 178.275(g)(3); bottom opening requirements: Prohibited. See 49 CFR 172.102(c)(7)(ii), Table of Portable Tank T Codes T1-T22.
TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.
TP2 a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP38 Each portable tank must be insulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials may not promote corrosion to steel when wet.
TP45 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. Thickness of stainless steel for portable tank shells and heads must be the greater of 6.35 mm (0.250 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.3 times the vapor pressure of the hazardous material at 46 °C (115 °F).

Source: 49 CFR 172.102 special provisions · eCFR, revision 2026-08-03

04 · Orange plate

The orange-coloured plate for UN 2692

The upper half of the plate carries the hazard identification number, the lower half the UN number. Dimensions follow ADR 5.3.2.2.1: 400 × 300 mm, black border and dividing line 15 mm, figures 100 mm high.

ADR orange-coloured plate: hazard identification number X88 above UN 2692 X88 2692

X88 — highly corrosive substance, which reacts dangerously with water.

8 Corrosivity
8 Corrosivity · doubled figure — intensification of that hazard
X The substance reacts dangerously with water. Water may only be used by approval of experts.

Source: ADR 2025, 5.3.2.3 · ECE/TRANS/352 Vol. II (UNECE). The tunnel restriction code of column (15) is a different value and is not part of our import.

05 · Substances

Substances shipped under UN 2692

Linked by CAS number, never by name: a name match once produced “acetone cyanohydrin” for acetone, and a wrong link here would be a wrong classification. Each entry opens its own reference page with the CLP classification and label elements.

06 · The label side

What UN 2692 looks like on a workplace label

The tables above are the transport classification. This is the other half of the same material: the CLP label elements of the substances linked to this number — what actually goes on the drum once it has been delivered. Transport marks and supply labels answer different regulations and do not replace one another.

Signal word across the linked substances: Danger

Hazard statements on the substances under UN 2692

H300 Fatal if swallowed.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.

Source: harmonised classification, EU CLP Annex VI. Transport classification and supply classification are decided under different rules and do not have to agree.

UN 2692 — frequently asked questions

What is UN 2692?

UN 2692 is the United Nations number for Boron tribromide. Under ADR 2025 it is assigned to class 8 (corrosive substances), classification code C1.

What packing group is UN 2692?

Under ADR 2025 UN 2692 is packing group I.

Is UN 2692 classified the same way in the United States and in Europe?

No. For UN 2692 the two tables differ on label codes. Each panel on this page shows its own source; values from one system must not be carried over into the other.

What is the hazard identification number for UN 2692?

The orange-coloured plate for UN 2692 carries the hazard identification number X88 above the UN number. Under ADR 5.3.2.3.2 that number means: highly corrosive substance, which reacts dangerously with water.

What is the transport category of UN 2692?

Column (15) of Table A puts UN 2692 in transport category 1. Under ADR 1.1.3.6.3 the maximum total quantity per transport unit for that category is 20.

Which substances ship under UN 2692?

We hold 1 substance linked to UN 2692 by CAS number. Each one has its own reference page with the CLP classification, GHS pictograms and hazard statements that apply on the label — the workplace side of the same material.

Need the plate, the labels or the placards printed?

The orange plate above is a physical article, and so are the class labels in column (5). Our sister site GHSLabels.com covers printing and suppliers. For the workplace label of the same material, use the GHS label constructor, and browse other numbers in the UN number reference.

Reference aid only. Values are reproduced from ADR 2025 and the 49 CFR 172.101 table as published; the consignor remains responsible for the classification of a specific consignment. Always verify against the current published regulation and the supplier's safety data sheet.

Get the free GHS / CLP / OSHA deadline calendar

Verified 2026–2029 compliance dates in one PDF — plus alerts when the rules change.