Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

N,N-Diethylaniline

N,N-Diethylaniline is a colorless to yellow liquid.

CAS 91-66-7 C10H15N 149.23 g/mol Danger

01 · Identification

What N,N-Diethylaniline is

N,N-Diethylaniline is a colorless to yellow liquid. Its molecular formula is C10H15N and its molecular weight is 149.23 g/mol. It boils at 216 °C, melts at -38.8 °C.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 2nd degree.

CAS number91-66-7
EC number202-088-8
Index number612-054-00-8
Molecular formulaC10H15N
Molecular weight149.23 g/mol
Chemical class Flammable agents - 2nd degree

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to N,N-Diethylaniline
CodeHazard statement
H331 Toxic if inhaled.
H311 Toxic in contact with skin.
H301 Toxic if swallowed.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements: P260, P270, P271, P273, P280, P301, P302, P304, P310, P314, P330, P352, P391, P501

03 · Physical and chemical properties

N,N-Diethylaniline properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 216.3 °C (421.3 °F) HSDB
215.5 °C (419.9 °F) at 760 mmHg CAMEO
216.3 °C (421.3 °F) at 760 mmHg DOE PAC
Melting point -38.8 °C (-37.8 °F) HSDB
-38.78 °C (-37.8 °F) CAMEO
-38 °C (-36.4 °F) ICSC
Density 0.906 g/cm³ CAMEO
0.93 g/cm³ ICSC
0.9307 g/cm³ at 20 °C HSDB
Solubility Sol in acetone HSDB
less than 1 mg/mL at 76.1 °F (NTP, 1992) at 24.5 °C CAMEO
In water, 139 mg/l @ 25 °C at 25 °C HSDB
Vapor pressure 0.1425 mmHg at 20 °C ICSC
0.14 mmHg at 25 °C HSDB
1 mmHg at 49.72 °C CAMEO
Flash point 85 °C (185 °F) HSDB
79 °C (174.2 °F) ICSC
Autoignition temperature 630 °C (1166 °F) HSDB
Vapor density 1 (air = 1) HSDB
5.1 (air = 1) ICSC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling N,N-Diethylaniline

Reactivity

N,N-DIETHYLANILINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check N,N-Diethylaniline in the storage compatibility matrix →

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