Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Isopentane

Isopentane is a volatile liquid or gas with a pleasant odor.

CAS 78-78-4 C5H12 72.15 g/mol Danger

01 · Identification

What Isopentane is

Isopentane is a volatile liquid or gas with a pleasant odor. Its molecular formula is C5H12 and its molecular weight is 72.15 g/mol. It boils at 27.8 °C, melts at -160 °C.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 4th degree.

CAS number78-78-4
EC number201-142-8
Index number601-085-00-2
Molecular formulaC5H12
Molecular weight72.15 g/mol
Chemical class Flammable agents - 4th degree

Other names for Isopentane

  • 2-methylbutane

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to Isopentane
CodeHazard statement
H224 Extremely flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

Supplemental EU statements: EUH066

Precautionary statements: P210, P233, P241, P242, P273, P391, P403, P501

03 · Physical and chemical properties

Isopentane properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 27.83 °C (82.1 °F) HSDB
27.78 °C (82 °F) at 760 mmHg CAMEO
28 °C (82.4 °F) ICSC
Melting point -159.8 °C (-255.6 °F) HSDB
-159.89 °C (-255.8 °F) CAMEO
-160 °C (-256 °F) ICSC
Density 0.6201 g/cm³ HSDB
0.6 g/cm³ ICSC
0.62 g/cm³ at 20 °C CAMEO
Solubility Insoluble in water HSDB
In water, 48 mg/L at 25 °C at 25 °C HSDB
In water, 49.6 mg/L at 25 °C at 25 °C HSDB
Vapor pressure 689 mmHg OSHA
595 mmHg at 21.1 °C DOE PAC
592.549 mmHg at 20 °C ICSC
Flash point -51 °C (-59.8 °F) HSDB
-56.67 °C (-70 °F) CAMEO
Autoignition temperature 420 °C (788 °F) HSDB
426.67 °C (800 °F) CAMEO
Lower explosive limit (LEL) 1.4 % by volume HSDB
Upper explosive limit (UEL) 7.6 % by volume HSDB
Vapor density 2.48 (air = 1) HSDB
2.5 (air = 1) ICSC
Odor threshold Odor Threshold Low: 400.0 [ppm] Haz-Map
Odor threshold from ACGIH Haz-Map
Critical temperature and pressure 187.25 °C (369.1 °F) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Isopentane

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature 2-8 °C Refrigerate before opening. Handle and open container with care.

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

Incompatible materials: Oxidizing agents.

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

ISOPENTANE is a fire and explosion hazard when in contact with oxidizing agents. (NTP, 1992).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Isopentane in the storage compatibility matrix →

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