Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2-ethoxyethyl acetate

2-ethoxyethyl acetate is a colorless liquid with a mild ester-like odor becomes objectionable in high concn.

CAS 111-15-9 C6H12O3 132.16 g/mol Danger

01 · Identification

What 2-ethoxyethyl acetate is

2-ethoxyethyl acetate is a colorless liquid with a mild ester-like odor becomes objectionable in high concn. Its molecular formula is C6H12O3 and its molecular weight is 132.16 g/mol. It boils at 156 °C, melts at -61.7 °C, is very soluble in water.

Under the GHS it carries the signal word Danger. It is classed as teratogens.

CAS number111-15-9
EC number203-839-2
Index number607-037-00-7
Molecular formulaC6H12O3
Molecular weight132.16 g/mol
Chemical class Teratogens

Other names for 2-ethoxyethyl acetate

  • ethylglycol acetate

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to 2-ethoxyethyl acetate
CodeHazard statement
H226 Flammable liquid and vapour.
H360FD May damage fertility. May damage the unborn child.
H332 Harmful if inhaled.
H312 Harmful in contact with skin.
H302 Harmful if swallowed.

Precautionary statements: P210, P233, P241, P242, P260, P270, P271, P280, P301, P302, P304, P312, P330, P352, P403

03 · Physical and chemical properties

2-ethoxyethyl acetate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 156.4 °C (313.5 °F) HSDB
156.11 °C (313 °F) NIOSH
156.11 °C (313 °F) at 760 mmHg CAMEO
Melting point -61.7 °C (-79.1 °F) HSDB
-61.67 °C (-79 °F) NIOSH
-61.72 °C (-79.1 °F) CAMEO
Density 0.98 g/cm³ NIOSH
0.975 g/cm³ at 20 °C HSDB
0.974 g/cm³ at 20 °C CAMEO
Solubility Very soluble in ethyl alcohol, ethyl ether HSDB
MISCIBLE WITH OLIVE OIL IN ALL PROP HSDB
Miscible with aromatic hydrocarbons HSDB
Vapor pressure 2 mmHg NIOSH
1.2 mmHg at 20 °C CAMEO
2 mmHg at 25 °C HSDB
Flash point 52 °C (125.6 °F) Closed cup HSDB
51.11 °C (124 °F) NIOSH
57.22 °C (135 °F) CAMEO
Autoignition temperature 379.44 °C (715 °F) HSDB
379 °C (714.2 °F) ICSC
Lower explosive limit (LEL) 1.7 % by volume HSDB
Upper explosive limit (UEL) 10 % by volume HSDB
6.7 % by volume CAMEO
14 % by volume ICSC
Vapor density 4.72 (air = 1) HSDB
4.7 (air = 1) ICSC
Odor threshold Odor Threshold Low: 0.06 [ppm] Haz-Map
Odor Threshold High: 0.13 [ppm] Haz-Map
Detection odor threshold from AIHA (mean = 0.06 ppm) Haz-Map
Critical temperature and pressure 333.89 °C (633 °F) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling 2-ethoxyethyl acetate

Storage conditions

MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMPOSE INTO TOXIC COMPONENTS ... SHOULD BE STORED IN A COOL WELL VENTILATED PLACE, OUT OF THE DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, AND SHOULD BE PERIODICALLY INSPECTED. INCOMPATIBLE MATERIALS SHOULD BE ISOLATED ...

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

Incompatibilities: Nitrates, strong oxidizers, strong alkalies, strong acids.

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

Mixing ETHYLENE GLYCOL MONOETHYL ETHER ACETATE in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, oleum, and vinyl acetate, NFPA 1991.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 2-ethoxyethyl acetate in the storage compatibility matrix →

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