Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Zineb

Zineb is powder or crystals from chloroform + alcohol and is odorless.

CAS 12122-67-7 C4H6N2S4Zn 275.8 g/mol Warning

01 · Identification

What Zineb is

Zineb is powder or crystals from chloroform + alcohol and is odorless. Its molecular formula is C4H6N2S4Zn and its molecular weight is 275.8 g/mol. It melts at 157 °C, is soluble in water.

Under the GHS it carries the signal word Warning. It is classed as mutagens.

CAS number12122-67-7
EC number235-180-1
Index number006-078-00-2
Molecular formulaC4H6N2S4Zn
Molecular weight275.8 g/mol
Chemical class Mutagens

Other names for Zineb

  • zineb (ISO)
  • zinc ethylenebis(dithiocarbamate) (polymeric)

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordWarning
Hazard statements assigned to Zineb
CodeHazard statement
H335 May cause respiratory irritation.
H317 May cause an allergic skin reaction.

Precautionary statements: P261, P272, P280, P313, P333

03 · Physical and chemical properties

Zineb properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point decomposes decomposes OSHA
Melting point 157 °C (314.6 °F) OSHA
157 °C (314.6 °F) decomposes, decomposes HSDB
Density Approx 1.74 at 20 °C at 20 °C HSDB
Solubility Soluble in carbon disulfide, pyridine HSDB
Soluble in chloroform HSDB
Soluble in benzene HSDB
Vapor pressure 1e-7 mmHg at 25 °C HSDB
7.4e-8 mmHg below this value OSHA
7.5e-8 mmHg below this value, at 20 °C HSDB
Flash point 90 °C (194 °F) ICSC
Autoignition temperature 149 °C (300.2 °F) HSDB
Lower explosive limit (LEL) Finely dispersed particles form explosive mixtures in air. HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Zineb

Storage conditions

Store in well-aired, fresh (less than 30 °C), dry area away from dwellings, animal shelters and stored food.

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

ZINEB is a zinc salt of a dithiocarbamic acid. May generate flammable gases with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Zineb in the storage compatibility matrix →

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