Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

N-2-naphthylaniline

N-2-naphthylaniline is needles from methanol.

CAS 135-88-6 C16H13N 219.28 g/mol Warning

01 · Identification

What N-2-naphthylaniline is

N-2-naphthylaniline is needles from methanol. Its molecular formula is C16H13N and its molecular weight is 219.28 g/mol. It boils at 396 °C, melts at 108 °C, is practically insoluble in water.

Under the GHS it carries the signal word Warning.

CAS number135-88-6
EC number205-223-9
Index number612-135-00-8
Molecular formulaC16H13N
Molecular weight219.28 g/mol

Other names for N-2-naphthylaniline

  • N-phenyl-2-naphthylamine

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordWarning
Hazard statements assigned to N-2-naphthylaniline
CodeHazard statement
H351 Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements: P201, P261, P264, P272, P273, P280, P302, P305, P308, P313, P332, P333, P337, P338, P352, P391, P501

03 · Physical and chemical properties

N-2-naphthylaniline properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 395.5 °C (743.9 °F) HSDB
395 °C (743 °F) NIOSH
395 °C (743 °F) at 760 mmHg CAMEO
Melting point 108 °C (226.4 °F) HSDB
107.78 °C (226 °F) NIOSH
Density 1.24 g/cm³ HSDB
Solubility SOLUBILITY IN ETHANOL 50 G/L, IN BENZENE 27 G/L, IN ACETONE 640 G/L HSDB
INSOL IN WATER; SOL IN ALC, ETHER, ACETIC ACID (BLUISH FLUORESCENCE) HSDB
Insoluble NIOSH
Vapor pressure 0.00000829 mmHg Haz-Map
Lower explosive limit (LEL) Combustible Solid NIOSH

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling N-2-naphthylaniline

Storage conditions

...MATERIALS WHICH ARE TOXIC AS STORED OR WHICH...DECOMP INTO TOXIC COMPONENTS DUE TO CONTACT WITH HEAT...SHOULD BE STORED IN COOL, WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, &...PERIODICALLY INSPECTED & MONITORED.

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

Oxidizers.

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

N-PHENYL-2-NAPHTHYLAMINE may react with strong oxidizing agents (NTP, 1992). Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check N-2-naphthylaniline in the storage compatibility matrix →

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