Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Hydrazobenzene

Hydrazobenzene is a tablets from alcohol and ether.

CAS 122-66-7 C12H12N2 184.24 g/mol Danger

01 · Identification

What Hydrazobenzene is

Hydrazobenzene is a tablets from alcohol and ether. Its molecular formula is C12H12N2 and its molecular weight is 184.24 g/mol. It boils at 293 °C, melts at 131 °C.

Under the GHS it carries the signal word Danger. It is classed as hazardous Air Pollutants (HAPs).

CAS number122-66-7
EC number204-563-5
Index number007-021-00-4
Molecular formulaC12H12N2
Molecular weight184.24 g/mol
Chemical class Hazardous Air Pollutants (HAPs)

Other names for Hydrazobenzene

  • 1,2-diphenylhydrazine

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to Hydrazobenzene
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements: P201, P270, P273, P280, P301, P308, P312, P313, P330, P391, P501

03 · Physical and chemical properties

Hydrazobenzene properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 293 °C (559.4 °F) at 760 mmHg HSDB
Decomposes (NTP, 1992) decomposes CAMEO
Melting point 131.11 °C (268 °F) CAMEO
131 °C (267.8 °F) DOE PAC
131 °C (267.8 °F) decomposes HSDB
Density 1.16 g/cm³ ICSC
1.158 g/cm³ at 16.11 °C CAMEO
1.158 g/cm³ at 16 °C HSDB
Solubility Slightly sol in benzene, deuterated dimethyl sulfoxide; insol in acetic acid; very soluble in ethanol HSDB
Solubility in water, g/100ml at 20 °C: at 20 °C ICSC
In water, 221 mg/L at 25 °C at 25 °C HSDB
Vapor pressure 0.00044 mmHg at 25 °C HSDB
0.00044 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Hydrazobenzene

Storage conditions

PRECAUTIONS FOR "CARCINOGENS": Storage site should be as close as practicable to lab in which carcinogens are to be used, so that only small quantities required for ... expt need to be carried. Carcinogens should be kept in only one section of cupboard, an explosion proof refrigerator or freezer (depending on chemicophysical properties ...) that bears appropriate label. An inventory ... should be kept, showing quantity of carcinogen & date it was acquired ... Facilities for dispensing ... should be contiguous to storage area. /Chemical Carcinogens/

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

Toxic gases may be formed by mixing DIPHENYLHYDRAZINE with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Hydrazobenzene in the storage compatibility matrix →

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