Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Chlorocresol

Chlorocresol is dimorphous crystals aqueous solutions turn yellow on exposure to light and air and is odorless.

CAS 59-50-7 Danger

01 · Identification

What Chlorocresol is

Chlorocresol is dimorphous crystals aqueous solutions turn yellow on exposure to light and air and is odorless. It boils at 235 °C, melts at 67 °C, is soluble in water.

Under the GHS it carries the signal word Danger.

CAS number59-50-7
EC number200-431-6
Index number604-014-00-3

Other names for Chlorocresol

  • 4-chloro-m-cresol
  • 4-chloro-3-methylphenol

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to Chlorocresol
CodeHazard statement
H302 Harmful if swallowed.
H335 May cause respiratory irritation.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements: P260, P261, P270, P272, P273, P280, P301, P305, P310, P312, P313, P330, P331, P333, P338, P391, P501

03 · Physical and chemical properties

Chlorocresol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 235 °C (455 °F) HSDB
235 °C (455 °F) at 760 mmHg CAMEO
Melting point 67 °C (152.6 °F) HSDB
55.5 °C (131.9 °F) ligroin HSDB
66.11 °C (151 °F) CAMEO
Density 1.37 g/cm³ HSDB
1.4 g/cm³ ICSC
0.9 g/cm³ at 25 °C CAMEO
Solubility Soluble in alkalies, organic solvents, fats, and oils HSDB
One gram dissolves in 260 mL water at 20 °C at 20 °C HSDB
Vapor pressure 0.05 mmHg at 20 °C HSDB
0.05 mmHg Haz-Map
Flash point 110 °C (230 °F) CAMEO
118 °C (244.4 °F) ICSC
Autoignition temperature 590 °C (1094 °F) ICSC
Odor threshold detection: 0.1 mg/kg HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Chlorocresol

Incompatible materials

p-Chloro-m-cresol is corrosive to metals and forms complex compounds with transition metal ions. Slow discoloration of the chemical occurs in the presence of sunlight.

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

CHLOROCRESOLS are incompatible with bases, acid chlorides, acid anhydrides, and oxidizing agents. Corrodes steel, brass, copper and copper alloys (NTP, 1992).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Chlorocresol in the storage compatibility matrix →

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