Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

Build a label

Substance profile

Butyl nitrite

Butyl nitrite is a chemical substance with the molecular formula C4H9NO2.

CAS 544-16-1 C4H9NO2 103.12 g/mol Danger

01 · Identification

What Butyl nitrite is

Butyl nitrite is a chemical substance with the molecular formula C4H9NO2. Its molecular formula is C4H9NO2 and its molecular weight is 103.12 g/mol.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 3rd degree.

CAS number544-16-1
EC number208-862-1
Index number007-016-00-7
Molecular formulaC4H9NO2
Molecular weight103.12 g/mol
Chemical class Flammable agents - 3rd degree

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to Butyl nitrite
CodeHazard statement
H225 Highly flammable liquid and vapour.
H331 Toxic if inhaled.
H301 Toxic if swallowed.

Precautionary statements: P210, P233, P241, P242, P260, P270, P271, P301, P304, P310, P330, P403

03 · Physical and chemical properties

Butyl nitrite properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Vapor pressure 81.3 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Butyl nitrite

Reactivity

BUTYL NITRITE is an oxidizing agent but can serve as a reducing agent. May begin a vigorous reaction that culminates in a detonation if mixed with reducing agents, including hydrides, sulfides, nitrides, ammonium salts, cyanides, and many fuels.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Butyl nitrite in the storage compatibility matrix →

Get the free GHS / CLP / OSHA deadline calendar

Verified 2026–2029 compliance dates in one PDF — plus alerts when the rules change.