Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

Build a label

Substance profile

4-Methylimidazole

4-Methylimidazole is crystals.

CAS 822-36-6 C4H6N2 82.1 g/mol Danger

01 · Identification

What 4-Methylimidazole is

4-Methylimidazole is crystals. Its molecular formula is C4H6N2 and its molecular weight is 82.1 g/mol. It boils at 263 °C, melts at 56 °C, is very soluble in water.

Under the GHS it carries the signal word Danger.

CAS number822-36-6
EC number212-497-3
Index number613-349-00-4
Molecular formulaC4H6N2
Molecular weight82.1 g/mol

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to 4-Methylimidazole
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H360Fd May damage fertility. Suspected of damaging the unborn child.

Precautionary statements: P201, P280, P308, P313

03 · Physical and chemical properties

4-Methylimidazole properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 263 °C (505.4 °F) HSDB
263 °C (505.4 °F) at 760 mmHg DOE PAC
Melting point 56 °C (132.8 °F) HSDB
Density 1.0416 g/cm³ at 14 °C HSDB
Solubility Very soluble in ethanol HSDB
Vapor pressure 0.01 mmHg Haz-Map
Flash point 157 °C (314.6 °F) HSDB
Autoignition temperature 555 °C (1031 °F) HSDB
Lower explosive limit (LEL) Explosive limits 1.8-10.7 Vol. % HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling 4-Methylimidazole

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep in a dry place.

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

Materials to avoid: Strong oxidizing agents, acids, acid chlorides, acid anhydrides.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check 4-Methylimidazole in the storage compatibility matrix →

Get the free GHS / CLP / OSHA deadline calendar

Verified 2026–2029 compliance dates in one PDF — plus alerts when the rules change.