Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

4-Methyl-2-Pentanol

4-Methyl-2-Pentanol is a colorless liq with a mild odor.

CAS 108-11-2 C6H14O 102.17 g/mol Warning

01 · Identification

What 4-Methyl-2-Pentanol is

4-Methyl-2-Pentanol is a colorless liq with a mild odor. Its molecular formula is C6H14O and its molecular weight is 102.17 g/mol. It boils at 133 °C, melts at -90 °C, is miscible with water.

Under the GHS it carries the signal word Warning. It is classed as flammable agents - 2nd degree.

CAS number108-11-2
EC number203-551-7
Index number603-008-00-8
Molecular formulaC6H14O
Molecular weight102.17 g/mol
Chemical class Flammable agents - 2nd degree

Other names for 4-Methyl-2-Pentanol

  • 4-methylpentan-2-ol
  • methyl isobutyl carbinol

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordWarning
Hazard statements assigned to 4-Methyl-2-Pentanol
CodeHazard statement
H226 Flammable liquid and vapour.
H335 May cause respiratory irritation.

Precautionary statements: P210, P233, P241, P242, P403

03 · Physical and chemical properties

4-Methyl-2-Pentanol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 133 °C (271.4 °F) at 760 mmHg HSDB
132.78 °C (271 °F) NIOSH
131.78 °C (269.2 °F) at 760 mmHg CAMEO
Melting point -90 °C (-130 °F) HSDB
Density 0.81 g/cm³ NIOSH
0.8075 g/cm³ at 20 °C HSDB
0.807 g/cm³ at 20 °C CAMEO
Solubility SOL IN ALC & ETHER. HSDB
MISCIBLE WITH MOST COMMON ORG SOLVENTS. HSDB
Water solubility of 1.64X10+4 mg/kg (experimental). HSDB
Vapor pressure 3 mmHg NIOSH
2.8 mmHg at 20 °C HSDB
Flash point 40.56 °C (105 °F) HSDB
41.11 °C (106 °F) NIOSH
Lower explosive limit (LEL) 1 % by volume NIOSH
Upper explosive limit (UEL) 5.5 % by volume NIOSH
Vapor density 3.5 (air = 1) ICSC
Odor threshold Odor Threshold Low: 0.01 [ppm] Haz-Map
Odor Threshold High: 1.0 [ppm] Haz-Map
Odor threshold from "Quick Guide: The Electronic NIOSH Pocket Guide to Chemical Hazards" Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling 4-Methyl-2-Pentanol

Incompatible materials

Strong oxidizers.

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

METHYL ISOBUTYL CARBINOL is an alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 4-Methyl-2-Pentanol in the storage compatibility matrix →

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