Transport reference
UN 2206 — Isocyanates, toxic, N.O.S. or isocyanate solution, toxic, N.O.S.
Table A of ADR 2025 and the 49 CFR 172.101 Hazardous Materials Table for this number, kept side by side and never merged, plus the CLP label elements of the substances that ship under it.
The two tables are never merged. The same UN number can carry a different packing group, a different proper shipping name and entirely different special provisions in each system. Every value below sits under the name of the jurisdiction it comes from.
01 · Two jurisdictions
UN 2206 in ADR 2025 and in 49 CFR 172.101
The two systems differ for this number on 1 of 5 fields. Special provisions are deliberately absent from this comparison: identical code numbers mean different things in the two systems.
| Field | ADR 2025 Table A, Chapter 3.2 | 49 CFR 172.101 eCFR 2026-08-03 |
|---|---|---|
| Proper shipping name | ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. | Isocyanates, toxic, n.o.s. or Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C |
| Class or division | 6.1 | 6.1 |
| Packing group | II, III | II, III |
| Label codes | 6.1 | 6.1 |
| Rows in the table | 2 | 2 |
Sources: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE) · 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03
02 · ADR 2025
UN 2206 in Table A of ADR 2025
2 separate rows in Table A of Chapter 3.2. They are not interchangeable: the packing group follows from the properties of the consignment, and each row carries its own transport category — that is a different multiplier in the 1.1.3.6 calculation.
| Proper shipping name (3.1.2) | Class | Classification code | PG | Labels | Transport category | Hazard ID |
|---|---|---|---|---|---|---|
| ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. | 6.1 | T1 | II | 6.1 | 2 | 60 |
| ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. | 6.1 | T1 | III | 6.1 | 2 | 60 |
Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 6.1 is “Toxic substances” (ADR 2.1.1.1).
Transport category and the 1 000-point exemption
Column (15) of Table A decides whether a load stays under the exemption of ADR 1.1.3.6. Quantities of different categories are added with the multipliers below, and the sum must not exceed 1 000.
| Category | Max total quantity per transport unit | Multiplier in 1.1.3.6.4 | What it means |
|---|---|---|---|
| 2 | 333 | × 3 | Packing group II and the listed classes. |
Source: ADR 2025, 1.1.3.6.3 and 1.1.3.6.4 · ECE/TRANS/352 Vol. I (UNECE).
Special provisions — ADR 2025, Chapter 3.3
Codes from column (6) of Table A, with the text of Chapter 3.3.1. These are ADR provisions only. A code with the same number exists in 49 CFR 172.102 and means something else there — the two lists are never combined.
| SP 274 | The provisions of 3.1.2.8 apply. |
| SP 551 | Solutions of these isocyanates having a flash-point below 23 °C are substances of Class 3. |
Source: ADR 2025, Chapter 3.3 special provisions · ECE/TRANS/352 Vol. I (UNECE)
Carriage provisions — CV codes
| CV13 | Any leaked/spilled substance must be cleaned up before the unit is reused. |
| CV28 | Must be segregated from foodstuffs, other consumables and animal feed (7.5.4). · relevant to segregation on the vehicle |
Source: ADR 2025, 7.5.11 · ECE/TRANS/352 Vol. II (UNECE)
Not imported and therefore not shown for this number: limited quantities (column 7a), excepted quantities (7b), packing instructions (8), tank codes (10–13) and the tunnel restriction code (15). An empty section is more honest than borrowed text.
03 · United States
UN 2206 in the 49 CFR 172.101 Hazardous Materials Table
2 separate rows in the Hazardous Materials Table. Where the rows differ only by the symbol in column (1), that symbol is what tells them apart — “D” is domestic-only, “I” is international.
| Symbols (1) | Proper shipping name (2) | Class (3) | PG (5) | Labels (6) | Packaging (8) | Quantity limits (9) | Vessel stowage (10) |
|---|---|---|---|---|---|---|---|
| G | Isocyanates, toxic, n.o.s. or Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C | 6.1 | II | 6.1 | §173.153 · §173.202 · §173.243 | 5 L passenger 60 L cargo | E · 25, 40 |
| G | Isocyanates, toxic, n.o.s. or Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C | 6.1 | III | 6.1 | §173.153 · §173.203 · §173.241 | 60 L passenger 220 L cargo | E · 25, 40 |
Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 6.1 is “Poisonous materials” (49 CFR 173.2). Packaging cells are section references into 49 CFR part 173: exceptions, non-bulk, bulk. Handling codes in column 10B are defined in 49 CFR 176.84, which is not part of our import — the numbers are shown as printed in the table.
What the column (1) symbols mean
| G | Technical name required. A proper shipping name for which one or more technical names of the hazardous material must be entered in parentheses, in association with the basic description (see § 172.203(k)). |
Source: 49 CFR 172.101(b) · eCFR, revision 2026-08-03
Vessel stowage categories on this entry
| E | May be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel within the 25-passenger limit; prohibited on a passenger vessel above that limit. |
Source: 49 CFR 172.101(k) · eCFR, revision 2026-08-03
Special provisions — 49 CFR 172.102
Codes from column (7) of the Hazardous Materials Table, with the text of § 172.102. These are United States provisions only and have nothing to do with the ADR codes above, even where the number is identical.
| IB2 | Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). |
| IB3 | Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). |
| T11 | Portable tank instruction. Minimum test pressure: 6 bar; minimum shell thickness (reference steel): § 178.274(d)(2); pressure-relief requirements: Normal; bottom opening requirements: § 178.275(d)(3). See 49 CFR 172.102(c)(7)(ii), Table of Portable Tank T Codes T1-T22. |
| T7 | Portable tank instruction. Minimum test pressure: 4 bar; minimum shell thickness (reference steel): § 178.274(d)(2); pressure-relief requirements: Normal; bottom opening requirements: § 178.275(d)(3). See 49 CFR 172.102(c)(7)(ii), Table of Portable Tank T Codes T1-T22. |
| TP1 | The maximum degree of filling must not exceed the degree of filling determined by the following: |
| TP13 | Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. |
| TP2 | a. The maximum degree of filling must not exceed the degree of filling determined by the following: |
| TP27 | A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. |
| TP28 | A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. |
Source: 49 CFR 172.102 special provisions · eCFR, revision 2026-08-03
04 · Orange plate
The orange-coloured plate for UN 2206
The upper half of the plate carries the hazard identification number, the lower half the UN number. Dimensions follow ADR 5.3.2.2.1: 400 × 300 mm, black border and dividing line 15 mm, figures 100 mm high.
60 — toxic or slightly toxic substance.
| 6 | Toxicity or risk of infection |
| 0 | No further hazard — the first figure alone describes the hazard adequately |
Source: ADR 2025, 5.3.2.3 · ECE/TRANS/352 Vol. II (UNECE). The tunnel restriction code of column (15) is a different value and is not part of our import.
05 · FAQ
UN 2206 — frequently asked questions
What is UN 2206?
UN 2206 is the United Nations number for Isocyanates, toxic, N.O.S. or isocyanate solution, toxic, N.O.S.. Under ADR 2025 it is assigned to class 6.1 (toxic substances), classification code T1.
What packing group is UN 2206?
Table A of ADR 2025 lists UN 2206 under 2 packing groups — II, III — as separate rows. The packing group follows from the properties of the specific consignment; it is not interchangeable, and each row carries its own transport category.
Is UN 2206 classified the same way in the United States and in Europe?
No. For UN 2206 the two tables differ on proper shipping name. Each panel on this page shows its own source; values from one system must not be carried over into the other.
What is the hazard identification number for UN 2206?
The orange-coloured plate for UN 2206 carries the hazard identification number 60 above the UN number. Under ADR 5.3.2.3.2 that number means: toxic or slightly toxic substance.
What is the transport category of UN 2206?
Column (15) of Table A puts UN 2206 in transport category 2. Under ADR 1.1.3.6.3 the maximum total quantity per transport unit for that category is 333.
Need the plate, the labels or the placards printed?
The orange plate above is a physical article, and so are the class labels in column (5). Our sister site GHSLabels.com covers printing and suppliers. For the workplace label of the same material, use the GHS label constructor, and browse other numbers in the UN number reference.
Reference aid only. Values are reproduced from ADR 2025 and the 49 CFR 172.101 table as published; the consignor remains responsible for the classification of a specific consignment. Always verify against the current published regulation and the supplier's safety data sheet.