Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Sodium carbonate

Sodium carbonate is grayish-white powder or lumps containing up to 99% sodium carbonate and is odorless.

CAS 497-19-8 CNa2O3 105.988 g/mol Warning

Sodium carbonate Safety Data Sheet →

01 · Identification

What Sodium carbonate is

Sodium carbonate is grayish-white powder or lumps containing up to 99% sodium carbonate and is odorless. Its molecular formula is CNa2O3 and its molecular weight is 105.988 g/mol. It melts at 856 °C.

Under the GHS it carries the signal word Warning.

CAS number497-19-8
EC number207-838-8
Index number011-005-00-2
Molecular formulaCNa2O3
Molecular weight105.988 g/mol

Other names for Sodium carbonate

  • soda ash
  • washing soda
  • Na2CO3

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordWarning
Hazard statements assigned to Sodium carbonate
CodeHazard statement
H319 Causes serious eye irritation.

Precautionary statements: P264, P280, P305, P313, P337, P338

03 · Physical and chemical properties

Sodium carbonate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point Decomposes on heating by CO2 loss decomposes HSDB
Melting point 856 °C (1572.8 °F) HSDB
851 °C (1563.8 °F) ICSC
Density 2.54 g/cm³ HSDB
4.7 g/cm³ HSDB
2.5 g/cm³ ICSC
Solubility Solubility in water at 0, 10, 20 and 30 °C is 6, 8.5, 17 and 28 wt %, respectively. HSDB
Soluble in water HSDB
In water, 30.7 g/100 g water at 25 °C at 25 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Sodium carbonate

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Hygroscopic. Keep in a dry place. Storage class (TRGS 510): Non Combustible Solids.

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

The anhydrous reaction of sodium carbonate & phosphorus pentoxide, initiated by local heating, can generate relatively high temp.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Sodium carbonate in the storage compatibility matrix →

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