Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Metam-sodium

Metam-sodium is white crystals.

CAS 137-42-8 Danger

01 · Identification

What Metam-sodium is

Metam-sodium is white crystals. It boils at 110 °C.

Under the GHS it carries the signal word Danger.

CAS number137-42-8
EC number205-293-0
Index number006-013-00-8

Other names for Metam-sodium

  • metam-sodium (ISO)
  • sodium methyldithiocarbamate

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to Metam-sodium
CodeHazard statement
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Supplemental EU statements: EUH031

Precautionary statements: P260, P261, P270, P272, P273, P280, P301, P310, P312, P313, P330, P331, P333, P391, P501

03 · Physical and chemical properties

Metam-sodium properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 110 °C (230 °F) Commercial product HSDB
Melting point Decomposes without melting decomposes HSDB
Solubility In acetone, ethanol, kerosene, xylene < 5 g/L. Practically insoluble in most other organic solvents. HSDB
In water, 7.22X10+5 mg/L at 20 °C at 20 °C HSDB
Moderately soluble in alcohol; stable in concentrated aqueous solution but decomposes in dilute aqueous solutions decomposes HSDB
Vapor pressure Non-volatile HSDB
Lower explosive limit (LEL) Non flammable. Metham Sodium Dihydrate HSDB
Corrosivity THE AQUEOUS SOLUTION IS CORROSIVE TO BRASS, COPPER AND ZINC HSDB
Aluminum, very rapid corrosion; mild steel, 0.7 mg/day/sq m; stainless steel, <0.2 mg/day/sq m HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Metam-sodium

Storage conditions

Store in a cool, dry place. Keep container closed when not in use. Do not store below 32 dg F. Product crystalizes at lower tempratures. Warm or store at higher tempratures and mix to redissolve crystals and assure uniformity before use. /Vapam/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Metam-sodium in the storage compatibility matrix →

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