Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Fluorosilicic acid

Fluorosilicic acid is a transparent, colorless, fuming liquid with a sour, pungent odor.

CAS 16961-83-4 F6H2Si 144.091 g/mol Danger

01 · Identification

What Fluorosilicic acid is

Fluorosilicic acid is a transparent, colorless, fuming liquid with a sour, pungent odor. Its molecular formula is F6H2Si and its molecular weight is 144.091 g/mol. It boils at 100 °C, melts at -20 °C.

Under the GHS it carries the signal word Danger. It is classed as corrosives.

CAS number16961-83-4
EC number241-034-8
Index number009-011-00-5
Molecular formulaF6H2Si
Molecular weight144.091 g/mol
Chemical class Corrosives

Other names for Fluorosilicic acid

  • fluorosilicic acid ... %

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to Fluorosilicic acid
CodeHazard statement
H314 Causes severe skin burns and eye damage.

Precautionary statements: P260, P280, P301, P310, P331

03 · Physical and chemical properties

Fluorosilicic acid properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 100 °C (212 °F) at 760 mmHg CAMEO
Decomposes. (USCG, 1999) decomposes CAMEO
Melting point -20 °C (-4 °F) CAMEO
Density 1.25 g/cm³ CAMEO
1.4634 g/cm³ at 25 °C HSDB
1.3 g/cm³ at 25 °C, approx. CAMEO
Solubility DECOMP AT MP; DELIQUESCENT; WHITE CRYSTALS; SOL IN ALKALI; SOL IN COLD AND HOT WATER DIHYDRATE HSDB
SOL IN COLD & HOT WATER; SLIGHTLY IN ALKALI HSDB
Solubility in water: miscible ICSC
Corrosivity Attacks glass and stoneware HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Fluorosilicic acid

Storage conditions

The more concentrated solution (but not the anhydrous liquid) can be stored in glass, although some etching will take place around the surface. Usually stored in iron containers.

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

Will react with water or steam to produce toxic and corrosive fumes.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Fluorosilicic acid in the storage compatibility matrix →

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