Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Diisopropylamine

Diisopropylamine is a colorless liquid with an ammonia or fish-like odor.

CAS 108-18-9 C6H15N 101.19 g/mol Danger

01 · Identification

What Diisopropylamine is

Diisopropylamine is a colorless liquid with an ammonia or fish-like odor. Its molecular formula is C6H15N and its molecular weight is 101.19 g/mol. It boils at 84 °C, melts at -61 °C, is very soluble in water.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 3rd degree.

CAS number108-18-9
EC number203-558-5
Index number612-129-00-5
Molecular formulaC6H15N
Molecular weight101.19 g/mol
Chemical class Flammable agents - 3rd degree

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordDanger
Hazard statements assigned to Diisopropylamine
CodeHazard statement
H225 Highly flammable liquid and vapour.
H332 Harmful if inhaled.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

Precautionary statements: P210, P233, P241, P242, P260, P270, P271, P280, P301, P304, P310, P312, P330, P331, P403

03 · Physical and chemical properties

Diisopropylamine properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 84 °C (183.2 °F) at 760 mmHg HSDB
83.89 °C (183 °F) NIOSH
83.89 °C (183 °F) at 760 mmHg CAMEO
Melting point -61 °C (-77.8 °F) HSDB
-96.11 °C (-141 °F) NIOSH
-61.11 °C (-78 °F) CAMEO
Density 0.72 g/cm³ NIOSH
0.7169 g/cm³ at 20 °C HSDB
0.717 g/cm³ at 20 °C CAMEO
Solubility Very soluble in acetone, benzene, ether, and ethanol. HSDB
Miscible NIOSH
In water, 1.1X10+5 mg/l @ 25 °C at 25 °C HSDB
Vapor pressure 70 mmHg NIOSH
129.25 mmHg CAMEO
79.4 mmHg at 25 °C HSDB
Flash point -1.11 °C (30 °F) HSDB
-6.67 °C (20 °F) NIOSH
Autoignition temperature 315.56 °C (600 °F) HSDB
316 °C (600.8 °F) ICSC
Lower explosive limit (LEL) 1.1 % by volume HSDB
Upper explosive limit (UEL) 7.1 % by volume HSDB
Vapor density 3.5 (air = 1) HSDB
Odor threshold Odor threshold = 1.8 ppm HSDB
Odor Threshold Low: 0.13 [ppm] Haz-Map
Detection odor threshold from AIHA (mean = 0.13 ppm) Haz-Map
Critical temperature and pressure 249 °C (480.2 °F) HSDB
Corrosivity MAY ATTACK SOME FORMS OF PLASTIC HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Diisopropylamine

Storage conditions

Store in a cool, dry, well-ventilated location. Separate from acids; oxidizing material, plastics.

Source: Hazardous Substances Data Bank (HSDB)

Incompatible materials

Strong oxidizers, strong acids.

Source: Hazardous Substances Data Bank (HSDB)

Reactivity

DIISOPROPYLAMINE can react violently with oxidizing agents and strong acids. Readily eutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Diisopropylamine in the storage compatibility matrix →

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