Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Butyl butyrate

Butyl butyrate: liquid.

CAS 109-21-7 C8H16O2 144.21 g/mol Warning

01 · Identification

What Butyl butyrate is

Butyl butyrate: liquid. Its molecular formula is C8H16O2 and its molecular weight is 144.21 g/mol. It boils at 167 °C, melts at -91.7 °C.

Under the GHS it carries the signal word Warning.

CAS number109-21-7
EC number203-656-8
Index number607-031-00-4
Molecular formulaC8H16O2
Molecular weight144.21 g/mol

02 · GHS classification

Hazards and label elements

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Signal wordWarning
Hazard statements assigned to Butyl butyrate
CodeHazard statement
H226 Flammable liquid and vapour.

Precautionary statements: P210, P233, P241, P242, P403

03 · Physical and chemical properties

Butyl butyrate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Property Value Conditions Source
Boiling point 166.67 °C (332 °F) at 760 mmHg CAMEO
166.67 °C (332 °F) OSHA
166 °C (330.8 °F) at 760 mmHg DOE PAC
Melting point -91.67 °C (-133 °F) CAMEO
-91.5 °C (-132.7 °F) HMDB
Density 0.872 g/cm³ OSHA
0.872 g/cm³ at 20 °C CAMEO
Solubility miscible with alcohol, ether, most vegetable oils; slightly soluble in propylene glycol, water JECFA
1 ml in 3 ml 70% alcohol (in ethanol) JECFA
0.5 mg/mL at 20 °C at 20 °C HMDB
Vapor pressure 10.34 mmHg CAMEO
1.81 mmHg Haz-Map
Flash point 53.33 °C (128 °F) CAMEO

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

04 · Handling and storage

Storing and handling Butyl butyrate

Reactivity

BUTYL BUTYRATE reacts with acids to liberate heat along with butyl alcohol and butyric acid. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by interaction with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides. May attack some forms of plastics (USCG, 1999).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Butyl butyrate in the storage compatibility matrix →

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